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In this study, magnetic mesoporous mono\u2010 and bifunctional samples (featuring amino and\/or thiol groups for dual simultaneous adsorption) are developed. It is established that the obtained samples exhibit a well\u2010developed specific surface area owing to the use of a precursor with a phenylene bridge in the synthesis (237\u2013980\u2009m<jats:sup>2<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>), with a total content of functional groups of up to 2.5\u2009mmol\u2009g<jats:sup>\u22121<\/jats:sup>. A comparison of water and benzene vapor adsorption revealed their rapid kinetics and equal hydrophilic\/hydrophobic balance for all the samples. The thiol\u2010functionalized sample proved to be the best in arsenic ions adsorption, while the bifunctional amino\/thiol sample demonstrated the highest performance during doxycycline adsorption.\u2009 In real water containing trace amounts of other metals, the bifunctional sample Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>\/\u2261OSi\u2013C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>\u2013SiO\u2261\/\u2261Si(CH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>NH<jats:sub>2<\/jats:sub>\/\u2261Si(CH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>SH showed its advantages, as the different types of active centers on its surface additionally bound nontarget contaminants.<\/jats:p>","DOI":"10.1002\/cplu.202500197","type":"journal-article","created":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T14:29:11Z","timestamp":1750084151000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Phenylene\u2010Bridged Magnetic Mesoporous Silica for Dual\u2010Target Elimination of Arsenic(III) and Doxycycline from Real Water"],"prefix":"10.1002","volume":"90","author":[{"given":"Nataliia","family":"Stoliarchuk","sequence":"first","affiliation":[{"name":"Department of Chemisorption and Hybrid Materials Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine  17 Oleha Mudraka Kyiv 03164 Ukraine"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1210-1525","authenticated-orcid":false,"given":"Veronika","family":"Tomina","sequence":"additional","affiliation":[{"name":"Department of Chemisorption and Hybrid Materials Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine  17 Oleha Mudraka Kyiv 03164 Ukraine"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Myroslava","family":"Muratova","sequence":"additional","affiliation":[{"name":"Department of Chemisorption and Hybrid Materials Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine  17 Oleha Mudraka Kyiv 03164 Ukraine"},{"name":"Faculty of Natural Sciences National University of Kyiv\u2010Mohyla Academy  2 Skovorody Kyiv 04655 Ukraine"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maksym","family":"Lisnichuk","sequence":"additional","affiliation":[{"name":"Department of Condensed Matter Physics Faculty of Science Institute of Physics Pavol Jozef \u0160af\u00e1rik University  9 Park Angelinum 04001 Kosice Slovak Republic"},{"name":"Division of Ceramic and Non\u2010metallic Systems Institute of Materials Research of Slovak Academy of Sciences  47 Watsonova 04001 Kosice Slovak Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0380-7689","authenticated-orcid":false,"given":"Miroslava","family":"Vaclavikova","sequence":"additional","affiliation":[{"name":"Department of Physical and Physico\u2010Chemical Methods of Mineral Processing Institute of Geotechnics of Slovak Academy of Sciences  45 Watsonova 04001 Kosice Slovak Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2559-5771","authenticated-orcid":false,"given":"Inna","family":"Melnyk","sequence":"additional","affiliation":[{"name":"Department of Physical and Physico\u2010Chemical Methods of Mineral Processing Institute of Geotechnics of Slovak Academy of Sciences  45 Watsonova 04001 Kosice Slovak Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,7,8]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2013.01.032"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2007.01.006"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2013.07.002"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2008.11.086"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2023.122188"},{"key":"e_1_2_8_7_1","unstructured":"Directive (EU) 2020\/2184 on the quality of water intended for human consumption.https:\/\/eur\u2010lex.europa.eu\/eli\/dir\/2020\/2184\/oj(accessed 2025\u201003\u201015)."},{"key":"e_1_2_8_8_1","unstructured":"Eurostat Statistics Explained.https:\/\/www.ec.europa.eu\/eurostat\/statistics\u2010explained\/index.php?title=Waste_statistics(accessed 2025\u201003\u201015)."},{"key":"e_1_2_8_9_1","unstructured":"Commission Implementing Decision (EU) 2022\/679 establishing a watch list of substances for Union\u2010wide monitoring in the field of water policy.https:\/\/eur\u2010lex.europa.eu\/legal\u2010content\/EN\/TXT\/?uri=CELEX%3A32022D0679(accessed 2025\u201003\u201015)."},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0883-2927(02)00018-5"},{"key":"e_1_2_8_11_1","first-page":"218","volume-title":"The Metabolism of Arsenite","author":"Santini J. 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