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Herein, a three\u2010step sequential reaction is shown from epoxides to dehydrogenated diols, catalyzed by a combination of commercially available ionic liquids and supported Pt species on charcoal (Pt\/C) in low amounts (&lt;0.05\u2009mol%). The process involves first carbonation of epoxides with CO<jats:sub>2<\/jats:sub>, followed by the opening of the carbonate with H<jats:sub>2<\/jats:sub>O, and then an acceptor\u2010less dehydrogenation reaction of the resulting diol to release H<jats:sub>2<\/jats:sub>. The inclusion of this last step in the one\u2010pot synthesis of diols from epoxides is, to the knowledge, unprecedented. Reactive and kinetic experiments for each individual step reveal the key role of CO<jats:sub>2<\/jats:sub> to avoid epoxide polymerizations and enable the synthesis of a clean diol for the final dehydrogenation reaction.<\/jats:p>","DOI":"10.1002\/cplu.202500203","type":"journal-article","created":{"date-parts":[[2025,4,27]],"date-time":"2025-04-27T22:34:33Z","timestamp":1745793273000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Sequential Catalytic Carbonation\u2013Hydrolysis\u2013Diol Dehydrogenation Reaction of Epoxides"],"prefix":"10.1002","volume":"90","author":[{"given":"Alejandro","family":"Lumbreras\u2010Teijeiro","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica (UPV\u2013CSIC) Universitat Polit\u00e8cnica de Val\u00e8ncia\u2013Agencia Estatal Consejo Superior de Investigaciones Cient\u00edficas  Avda. de los Naranjos s\/n 46022 Valencia 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