{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,12]],"date-time":"2025-11-12T06:45:45Z","timestamp":1762929945774,"version":"3.45.0"},"reference-count":41,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2025,6,30]],"date-time":"2025-06-30T00:00:00Z","timestamp":1751241600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["2153922","1834750","2335833"],"award-info":[{"award-number":["2153922","1834750","2335833"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006132","name":"Office of Science","doi-asserted-by":"publisher","award":["DE\u2010AC02\u201006CH11357"],"award-info":[{"award-number":["DE\u2010AC02\u201006CH11357"]}],"id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2025,11,10]]},"abstract":"<jats:p>\n                    An in\u2010depth study of donor\u2013acceptor (D\/A) interactions between the high\u2010dipole acceptor C\n                    <jats:sub>60<\/jats:sub>\n                    F\n                    <jats:sub>18<\/jats:sub>\n                    (A) and polycyclic aromatic hydrocarbon (PAH) donors\u2014pyrene, perylene, and coronene\u2014reveals a surprisingly strong PAH size influence on the D\/A complex stoichiometry and ordering in co\u2010crystals. The crystallographic study shows the tendency of D\/A mixtures to form stacked layered structures for the larger PAHs, perylene and coronene, while the role of aromatic \u03c0\u2013\u03c0 interactions diminishes, in contrast to the smaller pyrene\/C\n                    <jats:sub>60<\/jats:sub>\n                    F\n                    <jats:sub>18<\/jats:sub>\n                    system. The behavior of the layered\u2010D\/A assemblies is investigated by utilizing sequential deposition and co\u2010evaporation of C\n                    <jats:sub>60<\/jats:sub>\n                    F\n                    <jats:sub>18<\/jats:sub>\n                    and coronene on Au(111) surfaces. Scanning tunneling microscopy shows that the flat lying configuration adopted by coronene on the metal, which forms highly ordered close\u2010packed monolayers stabilized by the interaction between their \u03c0 electrons and the high density of gold surface states, hinders the formation of the ordered assemblies of the corresponding co\u2010crystal. The influence of the substrate plus the critical role played by electronic and steric effects in the co\u2010crystal formation are believed to cause the lack of viability. However, it is remarkable that, on the surface, adsorbed single C\n                    <jats:sub>60<\/jats:sub>\n                    F\n                    <jats:sub>18<\/jats:sub>\n                    molecules are well centered on top of one coronene molecule, facilitating charge transfer between D and A molecules.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500243","type":"journal-article","created":{"date-parts":[[2025,6,3]],"date-time":"2025-06-03T15:53:27Z","timestamp":1748966007000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Donor\u2013Acceptor Interactions of C\n                    <sub>60<\/sub>\n                    F\n                    <sub>18<\/sub>\n                    with Polycyclic Aromatic Hydrocarbons: Size Effects in Bulk Crystallization and Surface Constraints"],"prefix":"10.1002","volume":"90","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8436-0852","authenticated-orcid":false,"given":"Nicholas J.","family":"DeWeerd","sequence":"first","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins CO 80523 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8047-2945","authenticated-orcid":false,"given":"Sebastian","family":"Balser","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins CO 80523 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Long K.","family":"San","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins CO 80523 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rogger","family":"Palacios\u2010Rivera","sequence":"additional","affiliation":[{"name":"Institute of Materials Science of 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