{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,23]],"date-time":"2026-03-23T01:55:17Z","timestamp":1774230917071,"version":"3.50.1"},"reference-count":52,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T00:00:00Z","timestamp":1759708800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T00:00:00Z","timestamp":1759708800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2025,12,10]]},"abstract":"<jats:p>\n                    Developing systems that facilitate the conversion of solar energy into fuel by reducing carbon dioxide and producing hydrogen could bridge the gap between production and consumption. In this work, a new method to study the reaction intermediates of carbon dioxide reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) and hydrogen elimination reaction (HER) catalyzed by Cobalt(III) catalysts with high photocatalytic activity in a water\/acetonitrile solvent system is proposed. The optimization of the cobalt catalysts ([Co(acac)(bpy)(N\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ].H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:bold>1<\/jats:bold>\n                    , [Co(acac)(en)(N\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:bold>2<\/jats:bold>\n                    and [Co(acac)(2\u2010pic)(N\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:bold>3<\/jats:bold>\n                    ) for photocatalytic activities in visible light irradiation (&gt;420\u2009nm) is performed by varying solvents systems (v\/v) (CH\n                    <jats:sub>3<\/jats:sub>\n                    COCH\n                    <jats:sub>3<\/jats:sub>\n                    \/H\n                    <jats:sub>2<\/jats:sub>\n                    O, CH\n                    <jats:sub>3<\/jats:sub>\n                    CN\/H\n                    <jats:sub>2<\/jats:sub>\n                    O, DMF\/H\n                    <jats:sub>2<\/jats:sub>\n                    O, EtOH\/H\n                    <jats:sub>2<\/jats:sub>\n                    O and H\n                    <jats:sub>2<\/jats:sub>\n                    O), sacrificial electron donors (1\u2010benzyl\u20101,4\u2010dihydronicotinamide (BNAH), diethanolamine (DEOA), triethylamine (TEA), and triethanolamine (TEOA), photosensitizers (Eosin Y, Erythrosin B, Fluorescein (Fl), Rose Bengal, Rhodamine\u2010B, and Ru(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    (Ru)), pH (7\u201312.5) and different catalyst concentrations (0\u20132\u2009mM). The arrangement around the Cobalt(III) ion is an octahedral coordination geometry. A combination of experimental characterization and density functional theory (DFT) is used to identify the mechanism of the photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction. DFT calculations and experimental results for the photocatalytic activity of the catalysts\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>3<\/jats:bold>\n                    reveal the involvement of multi\u2010electron metal\u2010ligand exchange coupling in promoting CO\n                    <jats:sub>2<\/jats:sub>\n                    RR and HER, and provide a starting point for the integration of these strategies into catalyst design.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500305","type":"journal-article","created":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T23:34:10Z","timestamp":1759793650000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Acetylacetonate Derived Cobalt(III) Complexes as Photocatalysts and Electrocatalysts for Energy Conversion"],"prefix":"10.1002","volume":"90","author":[{"given":"Thamilarasan","family":"Vijayan","sequence":"first","affiliation":[{"name":"Department of Chemistry and Nano Science Ewha Womans University  Seoul 120 750 Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Abida","family":"Batool","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Nano Science Ewha Womans University  Seoul 120 750 Republic of Korea"},{"name":"Gradutate Program in Innovative Biomaterials Convergence Ewha Womans University  Seoul 03760 Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu Mi","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Nano Science Ewha Womans University  Seoul 120 750 Republic of Korea"},{"name":"Gradutate Program in Innovative Biomaterials Convergence Ewha Womans University  Seoul 03760 Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jinheung","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Nano Science Ewha Womans University  Seoul 120 750 Republic of Korea"},{"name":"Gradutate Program in Innovative Biomaterials Convergence Ewha Womans University  Seoul 03760 Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rodrigo","family":"Arancibia","sequence":"additional","affiliation":[{"name":"Laboratorio de Qu\u00edmica Inorg\u00e1nica y Organomet\u00e1lica Departamento de Qu\u00edmica Anal\u00edtica e Inorg\u00e1nica Facultad de Ciencias Qu\u00edmicas Universidad de Concepci\u00f3n  Concepci\u00f3n 4030000 Chile"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2400-8467","authenticated-orcid":false,"given":"Nallathambi","family":"Sengottuvelan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Centre for Distance and Online Education (CDOE) Alagappa University  Karaikudi Tamilnadu 630003 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