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Contact angle measurements, surface plasmon resonance analysis, and kinetic and thermodynamic studies indicate that the introduction of benzylamine modifies surface hydrophobicity and increases chemical affinity with organic pollutants. While \u03c0\u2013\u03c0 interactions may play a role, especially with aromatic contaminants, the sorption behavior is overall influenced by a combination of hydrophobic effects and increased molecular similarity with the target molecules. The grafted films demonstrated high adsorption capacities for methylene blue and chlorhexidine (163.9 and 217.4 mg\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively), along with excellent reusability and washability. Biodegradability tests confirmed complete degradation within 90 days. This work offers a sustainable strategy for producing advanced cellulose\u2010based adsorbents for efficient and ecofriendly wastewater treatment.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500398","type":"journal-article","created":{"date-parts":[[2025,8,19]],"date-time":"2025-08-19T12:10:16Z","timestamp":1755605416000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Aqueous\u2010Phase Surface Amidation of TEMPO\u2010CNF Films for Improved Adsorption of Organic Pollutants in Water"],"prefix":"10.1002","volume":"90","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-6419-1066","authenticated-orcid":false,"given":"Domenico","family":"Santandrea","sequence":"first","affiliation":[{"name":"Department of Molecular Sciences and Nanosystems Ca\u2019 Foscari University of Venice  Via Torino 155 30172 Venezia Italy"},{"name":"Department of Architecture and Industrial Design University of Campania \u201cLuigi Vanvitelli\u201d  Via San Lorenzo\u2010Abazia di San Lorenzo\u2014Aversa (CE) 81031 Napoli Italy"},{"name":"Consorzio Interuniversitario per le Reattivit\u00e0 Chimiche e La Catalisi (CIRCC)  Via C. 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