{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T15:21:58Z","timestamp":1783437718551,"version":"3.54.6"},"reference-count":46,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,9,23]],"date-time":"2025-09-23T00:00:00Z","timestamp":1758585600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,9,23]],"date-time":"2025-09-23T00:00:00Z","timestamp":1758585600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001501","name":"University Grants Commission","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001501","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2025,12,10]]},"abstract":"<jats:p>\n                    Valorization of biomass\u2010derived chemicals into high\u2010quality compounds and biofuels is enormously fundamental to diminish dependence on fossil\u2010based resources. Furfural is a bio\u2010based valuable compound which can be proficiently upgraded to 4\u2010(2\u2010furyl)\u20103\u2010buten\u20102\u2010one (\n                    <jats:bold>FAc<\/jats:bold>\n                    ) and 1,4\u2010pentadiene\u20103\u2010one, 1,5\u2010di\u20102\u2010furanyl (\n                    <jats:bold>F<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>Ac<\/jats:bold>\n                    ) via aldol condensation of furfural with acetone. In the present work, efficient Cu\u2010doped Mg\uf8ffAl layered double hydroxides (\n                    <jats:bold>LDH<\/jats:bold>\n                    )\n                    <jats:bold>nanocatalysts<\/jats:bold>\n                    are fabricated by coprecipitation and are exploited for furfural conversion to obtained\n                    <jats:bold>FAc<\/jats:bold>\n                    and\n                    <jats:bold>F<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>Ac<\/jats:bold>\n                    . The structure\u2013activity relationship is scrutinized by characterizing fresh and spent\n                    <jats:bold>nanocatalysts<\/jats:bold>\n                    via numerous techniques. The good correlation between the amount of weak acidic\u2010weak basic catalytic sites and\n                    <jats:bold>nanocatalysts<\/jats:bold>\n                    performance is established. The superior performance of\n                    <jats:bold>Cu\u20100.1 nanocatalyst<\/jats:bold>\n                    (Cu\u2010content\u2009=\u20091.85 wt%) in aldol condensation is attributed to the presence of optimum weak acidic sites (0.21\u2009mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and weak basic sites (0.36\u2009mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), synergistic acidic\u2010basic effect, nano\u2010sized\n                    <jats:bold>Cu(OH)<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>nanoparticles<\/jats:bold>\n                    (1.6\u2009nm), high BET surface area (181 m\n                    <jats:sup>2\u2009<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), and mesoporous architecture of material.\n                    <jats:bold>Cu\u20100.1 nanocatalyst<\/jats:bold>\n                    delivered 98%\n                    <jats:bold>FAc<\/jats:bold>\n                    selectivity with 100% furfural conversion at 85\u2009\u00b0C. Furthermore, at 100 \u00b0C, the\n                    <jats:bold>nanocatalyst<\/jats:bold>\n                    gives 55%\n                    <jats:bold>F<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>Ac<\/jats:bold>\n                    selectivity with 73% furfural conversion. The catalyst displays good recyclability (7 recycles) and stability. Plausible mechanistic pathway for transformation of furfural to\n                    <jats:bold>FAc<\/jats:bold>\n                    and\n                    <jats:bold>F<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>Ac<\/jats:bold>\n                    is proposed.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500416","type":"journal-article","created":{"date-parts":[[2025,9,23]],"date-time":"2025-09-23T14:36:38Z","timestamp":1758638198000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synergistic Effect of Acidic\u2010Basic Features of Copper\u2010Doped Layered Double Hydroxides Nanocatalysts in Valorization of Biomass\u2010Derived Furfural to Biofuels"],"prefix":"10.1002","volume":"90","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-2657-1997","authenticated-orcid":false,"given":"Nilesh G.","family":"Gode","sequence":"first","affiliation":[{"name":"Department of Chemistry Rashtrapita Mahatma Gandhi Arts &amp; Science College Gondwana University  Nagbhid Gadchiroli, Dist\u2010Chandrapur Maharashtra 441205 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6432-0842","authenticated-orcid":false,"given":"Atul S.","family":"Nagpure","sequence":"additional","affiliation":[{"name":"Department of Chemistry Rashtrapita Mahatma Gandhi Arts &amp; Science College Gondwana University  Nagbhid Gadchiroli, Dist\u2010Chandrapur Maharashtra 441205 India"},{"name":"Catalysis &amp; Inorganic Chemistry Division, CSIR\u2010National Chemical Laboratory Dr. Homi Bhabha Road Pune 411008 India"},{"name":"IHLR &amp; SS Anand Niketan College  Anandwan Warora, Dist\u2010Chandrapur Maharashtra 442914 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-9415-227X","authenticated-orcid":false,"given":"Suresh B.","family":"Rewatkar","sequence":"additional","affiliation":[{"name":"Department of Chemistry Dr. Ambedkar College of Arts, Commerce &amp; Science  Chandrapur Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-7105-2445","authenticated-orcid":false,"given":"Shailesh K.","family":"Bhagat","sequence":"additional","affiliation":[{"name":"Department of Chemistry Yashwantrao Chawhan Arts, Commerce &amp; Science College  Lakhandur, Dist\u2010Bhandara Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1869-5950","authenticated-orcid":false,"given":"Ganpat D.","family":"Deshmukh","sequence":"additional","affiliation":[{"name":"Department of Zoology Rashtrapita Mahatma Gandhi Arts &amp; Science College Gondwana University  Nagbhid Gadchiroli, Dist\u2010Chandrapur Maharashtra 441205 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3616-0527","authenticated-orcid":false,"given":"Ajay","family":"Saini","sequence":"additional","affiliation":[{"name":"Central Analytical Facilities Manipal University Jaipur  Jaipur\u2010Ajmer Express Highway, Dehmi Kalan, Near GVK Toll Plaza Jaipur Rajasthan 303007 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,23]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/gch2.201800028"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2012.08.028"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2009.09.019"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2024.113756"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie4024935"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2017.04.060"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp303631v"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-014-8702-5"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10934-023-01545-w"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-015-0504-8"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/jm9930301263"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs501510e"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2012.05.022"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200900060"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2RA21762G"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA19909C"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00776"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03111"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02308"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cp00729c"},{"key":"e_1_2_9_22_1","unstructured":"S. V. V.Chilukuri A. S.Nagpure N. S.Lucas 2017 Process for the Preparation of 2 5\u2010Dimethylfuran and Furfuryl Alcohol over Ruthenium Supported Catalysts. United States Patent No. US 9757713 B2."},{"key":"e_1_2_9_23_1","unstructured":"S. V. V.Chilukuri A. S.Nagpure 2021 Transition Metal(s) Catalyst Supported on Nitrogen\u2010Doped Mesoporous Carbon and Its use in Catalytic Transfer Hydrogenation Reactions. United States Patent No. US 11000831 B2."},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2022.110118"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202100552"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CY01376J"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SE00361A"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b02398"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3RA00906H"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar030064p"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2010.11.007"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SE00444A"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.9b01138"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2015.11.027"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-5813(12)60035-8"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/jctb.5787"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2018.10.094"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2010.11.059"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.3390\/cryst10090833"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2013.10.059"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal10121484"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2024.102440"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c16732"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC05762C"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202000112"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/sia.6239"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biomaterials.2018.05.055"}],"container-title":["ChemPlusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202500416","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cplu.202500416","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202500416","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,23]],"date-time":"2026-03-23T01:09:40Z","timestamp":1774228180000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cplu.202500416"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,23]]},"references-count":46,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2025,12,10]]}},"alternative-id":["10.1002\/cplu.202500416"],"URL":"https:\/\/doi.org\/10.1002\/cplu.202500416","archive":["Portico"],"relation":{},"ISSN":["2192-6506","2192-6506"],"issn-type":[{"value":"2192-6506","type":"print"},{"value":"2192-6506","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,23]]},"assertion":[{"value":"2025-06-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500416"}}