{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T10:24:48Z","timestamp":1790072688468,"version":"4.0.1"},"reference-count":41,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T00:00:00Z","timestamp":1787443200000},"content-version":"am","delay-in-days":365,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2025,8,23]],"date-time":"2025-08-23T00:00:00Z","timestamp":1755907200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,8,23]],"date-time":"2025-08-23T00:00:00Z","timestamp":1755907200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE\u20102319929"],"award-info":[{"award-number":["CHE\u20102319929"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006770","name":"American Chemical Society Petroleum Research Fund","doi-asserted-by":"publisher","award":["68563\u2010UNI10"],"award-info":[{"award-number":["68563\u2010UNI10"]}],"id":[{"id":"10.13039\/100006770","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100009937","name":"Reed College","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100009937","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2025,10,9]]},"abstract":"<jats:p>\n                    Fluorination of organoboronic ester adducts via B\u2009\u2190\u2009N coordination enables the formation of photoactive solids capable of [2\u2009+\u20092]\u2010photodimerization, or confinement of a hydrocarbon guest (i.e\n                    <jats:italic>.<\/jats:italic>\n                    , benzene). Specifically, self\u2010assembly of organoboronic acids with varying levels and patterns of fluorination with catechol and 4\u2010stilbazole resulted in T\u2010shaped B\u2009\u2190\u2009N adducts, that organize into either photoactive dimeric assemblies (2,4\u2010 and 3,5\u2010difluorophenlboronic acids) or photostable architectures that encapsulate benzene (2,4,6\u2010trifluorophenylboronic and 2,3,5,6\u2010tetrafluorophenylboronic acids). Combined crystallographic analysis, molecular modeling, and Hirshfeld surface analysis revealed the formation of photoactive adducts with up to two fluorine atoms to be driven by enhanced face\u2010to\u2010face [\u03c0\u2026\u03c0] stacking aided by [C\uf8ffH\u2026\u03c0] contacts, while [C\uf8ffH\u2026F], [C\uf8ffH\u2026O], and [C\uf8ffH\u2026\u03c0] contacts in adducts with higher fluorination level sustained the inclusion of benzene molecules in the lattice. These findings support fluorination of organoboron systems as an effective strategy for property engineering in molecular materials.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500434","type":"journal-article","created":{"date-parts":[[2025,8,23]],"date-time":"2025-08-23T10:53:56Z","timestamp":1755946436000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Fluorination Modulates Solid\u2010State Reactivity and Guest Confinement in Organoboronic Ester Adducts"],"prefix":"10.1002","volume":"90","author":[{"given":"Alaric","family":"Shaw","sequence":"first","affiliation":[{"name":"Department of Chemistry Reed College  Portland OR 97202\u20138199 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivan","family":"Bondarenko","sequence":"additional","affiliation":[{"name":"Department of Chemistry Reed College  Portland OR 97202\u20138199 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