{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T09:06:51Z","timestamp":1791277611732,"version":"4.1.0"},"reference-count":67,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2026,4,22]],"date-time":"2026-04-22T00:00:00Z","timestamp":1776816000000},"content-version":"vor","delay-in-days":21,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,1]],"date-time":"2026-04-01T00:00:00Z","timestamp":1775001600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:p>\n                    The mercuration\u2013iododemercuration reactions of some propargyl systems were explored. In the presence of mercury (II) acetate, propargyl derivatives reacted facilely with iodine. These interactions proceeded by two possible pathways included corresponding bridged and linear organomercury intermediates. Short\u2010chain alkyl propargyl ethers under mild conditions with mercury (II) acetate in an acetic acid (hexane or dichloromethane) medium with iodine resulted in a mixture of iodoalkyloxypropynes, diiodoalkyloxypropenyl acetates, diiodoalkyloxypropenes, and triiodoalkyloxypropenes. Acetoxymercuration\u2013iododemercuration of the obtained reactive iodoalkynes occurred more rapidly than terminal alkynes. Hexyl, heptyl propargyl ethers studied reactions took place under heating, and the products were both unsaturated diiodoacetates and\n                    <jats:italic>trans<\/jats:italic>\n                    \u2010monoiodoacetates in a mass ratio of approximately 1:1. Acetoxymercuration\u2013iododemercuration of prop\u20102\u2010yn\u20101\u2010yl acetate in acetic acid at room temperature led to (\n                    <jats:italic>E<\/jats:italic>\n                    )\n                    <jats:italic>\u2010<\/jats:italic>\n                    2,3\u2010diiodoallyl acetate, diiododiacetate, and\n                    <jats:italic>cis\u2010<\/jats:italic>\n                    ,\n                    <jats:italic>trans<\/jats:italic>\n                    \u2010monoiododiacetates. The researched reaction of propargyl alcohol in acetic acid at room temperature led to the mixture of triiodopropene and diiodopropene. The mercury (II) acetate\u2010mediated iodination of 2\u2010methylbut\u20103\u2010yn\u20102\u2010ol depends on the solvents nature and afforded corresponding mono\u2010, di\u2010, triiododerivatives. The mercuration\u2013iododemercuration of 2\u2010methylbut\u20103\u2010yn\u20102\u2010yl acetate in acetic acid at room temperature was special. This reaction result was the blend containing the product of triple bond indirect hydration and iodination of the methyl group, activated by the carbonyl.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500577","type":"journal-article","created":{"date-parts":[[2026,4,22]],"date-time":"2026-04-22T20:20:48Z","timestamp":1776889248000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Peculiarities of Mercuration\u2013Iododemercuration of Propargyl Derivatives"],"prefix":"10.1002","volume":"91","author":[{"given":"Kristine Valerik","family":"Balyan","sequence":"first","affiliation":[{"name":"Scientific Technological Center of Organic and Pharmaceutical Chemistry National Academy of Sciences of the Republic of Armenia  Yerevan Republic of Armenia"},{"name":"Department of Pharmaceutical Chemistry International Scientific Educational Center of NAS RA  Yerevan Republic of Armenia"},{"name":"Department of 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