{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T07:04:19Z","timestamp":1785135859238,"version":"3.55.0"},"reference-count":58,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T00:00:00Z","timestamp":1783987200000},"content-version":"vor","delay-in-days":13,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:p>\n                    In this work, we have synthesised and spectroscopically characterised an acyl hydrazone\u2010based chemosensor,\n                    <jats:bold>\n                      H\n                      <jats:sub>2<\/jats:sub>\n                      L\n                    <\/jats:bold>\n                    , through two intermediate steps. Remarkably, this chemosensor exhibits selective recognition of Zn(II) and Al(III) ions in 9:1 EtOH\u2013water and DMSO\u2013water media, respectively, among competing cations. Followed by an optical colour change, the presence of Zn(II) and Al(III) ions enhances the luminescence property of the probe\n                    <jats:bold>\n                      H\n                      <jats:sub>2<\/jats:sub>\n                      L\n                    <\/jats:bold>\n                    . The limit of detection for both ions is within the nanomolar range. As a practical advantage, the sensor can also be employed in several applications for easy, on\u2010site detection, such as paper strips, cotton buds, and fluorescent ink. The chelation\u2010enhanced fluorescence emission in the presence of two target cations is the primary reason for the increased emission intensity when both analytes are present. The probe\u2010analyte NMR titration confirms the deprotonation of H2L and its coordination to the target metal ions. The Job's plot and mass spectral data are used to assess the stoichiometric addition of the probe to the analyte. The high binding constants obtained for the probe\u2013analyte interactions confirm strong affinity between\n                    <jats:bold>\n                      H\n                      <jats:sub>2<\/jats:sub>\n                      L\n                    <\/jats:bold>\n                    and the target ion, which is further supported by the successful isolation and characterisation of the corresponding solid Zn(II) complex (complex\n                    <jats:bold>1<\/jats:bold>\n                    ).\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500728","type":"journal-article","created":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T06:29:16Z","timestamp":1784096956000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Design and Development of Solvent\u2010Sensitive Zn(II)\/Al(III) Responsive Chemosensor: Extension to the Real\u2010World Application"],"prefix":"10.1002","volume":"91","author":[{"given":"Manik","family":"Das","sequence":"first","affiliation":[{"name":"Department of Chemistry Natural Sciences Research Centre Prabhat Kumar College (Vidyasagar University) Contai  Purba Medinipur India"},{"name":"Department of Chemistry Jadavpur University  Kolkata India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mousumi","family":"Giri","sequence":"additional","affiliation":[{"name":"Department of Chemistry Natural Sciences Research Centre Prabhat Kumar College (Vidyasagar University) Contai  Purba Medinipur India"},{"name":"Department of Chemistry University of Calcutta  Kolkata India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Soumik","family":"Laha","sequence":"additional","affiliation":[{"name":"IICB  Kolkata India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bidhan Chandra","family":"Samanta","sequence":"additional","affiliation":[{"name":"Department of Chemistry Mugberia Gangadhar Mahavidyalaya  Purba Medinipur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1256-399X","authenticated-orcid":false,"given":"Tithi","family":"Maity","sequence":"additional","affiliation":[{"name":"Department of Chemistry Natural Sciences Research Centre Prabhat Kumar College (Vidyasagar University) Contai  Purba Medinipur India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,14]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12576-017-0521-4"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10534-022-00373-w"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.phrs.2023.107039"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.53388\/FH2023013"},{"key":"e_1_2_8_6_1","first-page":"28","article-title":"The Important Role of Zinc in Neurological Diseases","volume":"13","author":"The Li Y. L.","year":"2023","journal-title":"Biomolecules"},{"key":"e_1_2_8_7_1","first-page":"809","article-title":"Multifunctional Role of Zinc in Human Health: An Update","volume":"22","author":"Kiouri D. P.","year":"2023","journal-title":"EXCLI Journal"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.3390\/nu9121286"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.3390\/cells13161359"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.3390\/antiox8060164"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00775-014-1139-0"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rsurfi.2024.100360"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29133130"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s13762-025-06437-x"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00128-018-2441-2"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talo.2024.100317"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2006.05.030"},{"key":"e_1_2_8_18_1","first-page":"51","article-title":"Is Aluminum Exposure a Risk Factor for Neurological Disorders?","volume":"6","author":"Inan\u2010Eroglu E.","year":"2018","journal-title":"Journal of Research in Medical Sciences"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ecoenv.2025.118759"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1111\/bpa.12333"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1289\/ehp.8563141"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-021-14700-0"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-981-13-1370-7_3"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-021-14700-0"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10895-025-04442-4"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2014.03.003"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2014.03.063"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja064955e"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2018.09.034"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10904-018-1023-4"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29245903"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.7407"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5TC04533A"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10895-025-04627-x"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2024.141131"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1080\/10408347.2024.2418327"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2016.09.042"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4NJ05225K"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2023.115214"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2022.113817"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2021.113302"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b00475"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2022.114490"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2015.06.061"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2018.05.049"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2013.07.030"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA09954D"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2018.11.076"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2013.12.114"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2022.133310"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10895-021-02756-7"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT01512B"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2025.109136"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.5c00611"},{"key":"e_1_2_8_55_1","volume-title":"Gaussian 09, Revision A.02","author":"Frisch M. J.","year":"2009"},{"key":"e_1_2_8_56_1","first-page":"4729","article-title":"Assertion and Validation of the Performance of the B3LYP*B3LYP* Functional for the First Transition Metal Row and the G2 Test Set","volume":"11","author":"Oliver S.","year":"2002","journal-title":"The Journal of Chemical Physics"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.475855"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00440-X"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202401310"}],"container-title":["ChemPlusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202500728","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cplu.202500728","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.202500728","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T06:49:18Z","timestamp":1785134958000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cplu.202500728"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7]]},"references-count":58,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2026,7]]}},"alternative-id":["10.1002\/cplu.202500728"],"URL":"https:\/\/doi.org\/10.1002\/cplu.202500728","archive":["Portico"],"relation":{},"ISSN":["2192-6506","2192-6506"],"issn-type":[{"value":"2192-6506","type":"print"},{"value":"2192-6506","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7]]},"assertion":[{"value":"2025-11-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-26","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-14","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500728"}}