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Here, we demonstrate a hierarchical approach that employs halogen bonding to control the spatial arrangement of tetrahedral [Fe\n                    <jats:sub>4<\/jats:sub>\n                    L\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>8+<\/jats:sup>\n                    cages in the solid state. By incorporating perfluorinated halogen bond donors of varying geometry, we demonstrate selective modulation of cage packing motifs without disrupting the cage architecture. Structural analysis reveals that incorporation of 1,3,5\u2010triiodotrifluorobenzene disrupts the robust honeycomb arrangement, producing a distorted cubic lattice with significantly reduced cage density and potentially enhanced cavity accessibility. This approach offers a pathway to design tunable porous molecular solids, ultimately enabling the transfer of solution\u2010phase properties to the solid state for applications in catalysis, separations, and molecular recognition.\n                  <\/jats:p>","DOI":"10.1002\/cplu.202500730","type":"journal-article","created":{"date-parts":[[2026,2,19]],"date-time":"2026-02-19T10:31:12Z","timestamp":1771497072000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Controlling the Arrangement of [Fe\n                    <sub>4<\/sub>\n                    L\n                    <sub>6<\/sub>\n                    ]\n                    <sup>8+<\/sup>\n                    Cages in the Solid State"],"prefix":"10.1002","volume":"91","author":[{"given":"Marco","family":"Pandullo","sequence":"first","affiliation":[{"name":"Centre for Materials Chemistry School of Chemistry and Physics Queensland University of Technology  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