{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T05:26:37Z","timestamp":1790659597921,"version":"4.1.0"},"reference-count":66,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2026,5,8]],"date-time":"2026-05-08T00:00:00Z","timestamp":1778198400000},"content-version":"vor","delay-in-days":7,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,1]],"date-time":"2026-05-01T00:00:00Z","timestamp":1777593600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2026,5]]},"abstract":"<jats:p>\n                    Reactions of [{Ru(\n                    <jats:italic>p\u2010<\/jats:italic>\n                    cymene)Cl\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>2<\/jats:sub>\n                    ] with the four chosen pyrrole\u20102\u2010aldimine (HL\u2010R; R\u2009=\u2009OCH\n                    <jats:sub>3<\/jats:sub>\n                    , CH\n                    <jats:sub>3<\/jats:sub>\n                    , H, and Cl) ligand precursors in ethanol, using triethylamine as base, furnished complexes of the expected type, [Ru(\n                    <jats:italic>p\u2010<\/jats:italic>\n                    cymene)(L\u2010R)Cl], in good yields. The individual complexes are depicted as complex\n                    <jats:bold>1<\/jats:bold>\n                    (R\u2009=\u2009OCH\n                    <jats:sub>3<\/jats:sub>\n                    ),\n                    <jats:bold>2<\/jats:bold>\n                    (R\u2009=\u2009CH\n                    <jats:sub>3<\/jats:sub>\n                    ),\n                    <jats:bold>3<\/jats:bold>\n                    (R\u2009=\u2009H), and\n                    <jats:bold>4<\/jats:bold>\n                    (R\u2009=\u2009Cl). Molecular structures of complexes\n                    <jats:bold>2<\/jats:bold>\n                    ,\n                    <jats:bold>3<\/jats:bold>\n                    , and\n                    <jats:bold>4<\/jats:bold>\n                    were determined by X\u2010ray diffraction method, while the structure of complex\n                    <jats:bold>1<\/jats:bold>\n                    was optimized with DFT method. In their electronic spectra, all the complexes exhibited intense absorptions in the visible and ultraviolet regions, which were analyzed by TDDFT calculations. Electrochemical redox properties of the complexes were studied by cyclic voltammetry. Presence of the Ru\u2013Cl moiety in these complexes indicated their potential to function as a catalyst\u2010precursor in transfer\u2010hydrogenation of organic substrates, which was explored toward transfer\u2010hydrogenation of carbonyl compounds to the corresponding alcohols. Using 2\u2010propanol as the provider of hydrogen and complex\n                    <jats:bold>1<\/jats:bold>\n                    as catalyst, hydrogenation of a variety of aldehydes and ketones could be achieved under relatively mild conditions, furnishing primary and secondary alcohols in very good isolated yields. A plausible mechanism for the observed catalysis has been proposed.\n                  <\/jats:p>","DOI":"10.1002\/cplu.70176","type":"journal-article","created":{"date-parts":[[2026,5,8]],"date-time":"2026-05-08T22:26:16Z","timestamp":1778279176000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Ru\u2010Arene Complexes Bearing Chelated Pyrrole\u20102\u2010Aldiminate: Synthesis, Structure, and Catalytic Application for Transfer Hydrogenation of Carbonyl Compounds"],"prefix":"10.1002","volume":"91","author":[{"given":"Binoy","family":"Ghosh","sequence":"first","affiliation":[{"name":"Department of Chemistry Inorganic Chemistry Section Jadavpur University  Kolkata India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debopam","family":"Singha","sequence":"additional","affiliation":[{"name":"Department of Chemistry Inorganic Chemistry Section Jadavpur University  Kolkata India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anushri","family":"Chandra","sequence":"additional","affiliation":[{"name":"Department of Chemistry Inorganic Chemistry Section Jadavpur University  Kolkata India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6245-9752","authenticated-orcid":false,"given":"Samaresh","family":"Bhattacharya","sequence":"additional","affiliation":[{"name":"Department of Chemistry Inorganic Chemistry Section Jadavpur University  Kolkata India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,8]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cogsc.2021.100511"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00203"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10544b"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.09.033"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200800196"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60291a003"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules27154703"},{"key":"e_1_2_9_9_1","first-page":"1","article-title":"Recent Advances in Ru Catalyzed Transfer Hydrogenation and Its Future Perspectives, Ruthenium \u2010 An Element Loved by Researchers","author":"Tyagi 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