{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,6]],"date-time":"2026-09-06T04:11:36Z","timestamp":1788667896337,"version":"build-2803163510"},"reference-count":66,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T00:00:00Z","timestamp":1783468800000},"content-version":"vor","delay-in-days":7,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001409","name":"Department of Science and Technology, Ministry of Science and Technology, India","doi-asserted-by":"publisher","award":["DST\/INSPIRE Fellowship\/2021\/IF210170"],"award-info":[{"award-number":["DST\/INSPIRE Fellowship\/2021\/IF210170"]}],"id":[{"id":"10.13039\/501100001409","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:p>\n                    A low\u2010cost and highly selective benzyl alcohol (BA) oxidation process in water was established through the activation of peroxymonosulfate (PMS) by cobalt\u2010exchanged zeolite\u2010NaY catalyst, Co\u2010NaY. Different physicochemical and spectroscopic analyses confirmed the existence of cobalt(II) species as Co(OH)\n                    <jats:sub>2<\/jats:sub>\n                    in zeolite\u2010NaY framework. Zeolite\u2010NaY played a pivotal role in trapping the free radicals, activating the PMS, and stabilizing the active Co(peroxo) species, Co(O\u2013O). The involvement of Co(O\u2013O) species in the reaction mechanism was evidenced by characteristic spectroscopic analyses, including the FTIR band at 926\u2009cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    and the Raman band at 983\u2009cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , attributed to the \u03bd(O\u2013O) vibration through Fermi resonance. The formation of cobalt(oxo)(hydroxy) complex as the intermediate redox active centre was believed to help the BA oxidation reaction to proceed through a non\u2010free radical pathway. Noninvolvement of the free radical in the course of the reaction was evident from the electron paramagnetic resonance spectroscopic analysis. Benzaldehyde was selectively obtained up to 85% through the benzylic C\uf8ffH bond activation process in water making it a green reaction. Density functional theory calculations further supported the proposed mechanism, indicating that the reaction is thermodynamically favourable at 50\u00b0C in water. The catalyst exhibited good recyclability, maintaining product selectivity over three cycles.\n                  <\/jats:p>","DOI":"10.1002\/cplu.70207","type":"journal-article","created":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:28:56Z","timestamp":1783556936000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Selective Oxidation of Benzyl Alcohol in Water With Cobalt\u2010Exchanged Zeolite\u2010NaY Catalyst"],"prefix":"10.1002","volume":"91","author":[{"given":"Shamim","family":"Islam","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences Tezpur University  Tezpur Assam India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tonmoy J.","family":"Bora","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences Tezpur University  Tezpur Assam India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Donguk","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering Ulsan National Institute of Science and Technology  Ulsan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Young\u2010Bin","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering Ulsan National Institute of Science and Technology  Ulsan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kangkan","family":"Sarmah","sequence":"additional","affiliation":[{"name":"Department of Chemistry Cotton University  Guwahati Assam India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4370-8108","authenticated-orcid":false,"given":"Ankur K.","family":"Guha","sequence":"additional","affiliation":[{"name":"Department of Chemistry Cotton University  Guwahati Assam India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8971-8550","authenticated-orcid":false,"given":"Galla V.","family":"Karunakar","sequence":"additional","affiliation":[{"name":"Division of Fluro and Agro Chemicals CSIR\u2010Indian Institute of Chemical Technology  Hyderabad Telangana India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6535-3913","authenticated-orcid":false,"given":"Kusum K.","family":"Bania","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences Tezpur University  Tezpur Assam India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,8]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2022.231873"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2023.119254"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar400270x"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b00032"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoso.2020.100470"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2019.08.031"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.122447"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC01588J"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms14036"},{"key":"e_1_2_10_11_1","first-page":"75","volume-title":"Advanced Catalysis","author":"Dai C.","year":"2018"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b03819"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.3390\/chemistry7030081"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2010.06.013"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.04.067"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.3c06414"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c00476"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms4332"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b01197"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.5900"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.3390\/chemistry2010010"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms14839"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b01311"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp063506y"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b11086"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00644"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60025D"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2022.07.011"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05273"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2016.10.064"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2004.12.017"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/apj.599"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0CS00012D"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4940207"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3RA44355H"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04867"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp908548f"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp000540i"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp0623387"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2008.12.036"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2017.10.019"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal12121644"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2013.04.126"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.3c03244"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT01640A"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep23382"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021\u20109517(02)00153\u20107"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920\u20105861(01)00521\u20101"},{"key":"e_1_2_10_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2024.112552"},{"key":"e_1_2_10_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tca.2008.04.015"},{"key":"e_1_2_10_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/A908065A"},{"key":"e_1_2_10_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.123793"},{"key":"e_1_2_10_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.6b02147"},{"key":"e_1_2_10_54_1","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M203358200"},{"key":"e_1_2_10_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/0368\u20102048(89)85017\u20100"},{"key":"e_1_2_10_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2022.152672"},{"key":"e_1_2_10_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021\u20109517(80)90501\u20101"},{"key":"e_1_2_10_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2014.06.003"},{"key":"e_1_2_10_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2020.104268"},{"key":"e_1_2_10_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jtice.2019.06.021"},{"key":"e_1_2_10_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202304882"},{"key":"e_1_2_10_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2007.05.024"},{"key":"e_1_2_10_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2017.07.039"},{"key":"e_1_2_10_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2021.127520"},{"key":"e_1_2_10_65_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00214\u2010007\u20100401\u20108"},{"key":"e_1_2_10_66_1","volume-title":"Gaussian 16, Revision A.03","author":"Frisch M. J.","year":"2016"},{"key":"e_1_2_10_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2022.118816"}],"container-title":["ChemPlusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.70207","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cplu.70207","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cplu.70207","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T06:49:26Z","timestamp":1785134966000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cplu.70207"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7]]},"references-count":66,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2026,7]]}},"alternative-id":["10.1002\/cplu.70207"],"URL":"https:\/\/doi.org\/10.1002\/cplu.70207","archive":["Portico"],"relation":{},"ISSN":["2192-6506","2192-6506"],"issn-type":[{"value":"2192-6506","type":"print"},{"value":"2192-6506","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7]]},"assertion":[{"value":"2026-02-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-24","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70207"}}