{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T19:27:33Z","timestamp":1787686053818,"version":"build-2784847793"},"reference-count":78,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"vor","delay-in-days":10,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,1]],"date-time":"2026-08-01T00:00:00Z","timestamp":1785542400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2026,8]]},"abstract":"<jats:p>\n                    In this study, a novel Ni\u2013MoO\n                    <jats:sub>3<\/jats:sub>\n                    @MIL\u2010101(Cr) composite catalyst was synthesized via a one\u2010step hydrothermal method for the oxidative desulfurization (ODS) of dibenzothiophene (DBT). The catalyst combines the high specific surface area of MIL\u2010101(Cr) with the redox properties of Ni\u2013MoO\n                    <jats:sub>3<\/jats:sub>\n                    , providing an effective synergy between adsorption and catalytic oxidation. The incorporation of Ni as a promoter significantly enhances catalytic activity, enabling complete sulfur removal (\u223c100%) under mild conditions (50\u2009\u00b0C) within 60\u2009min. Structural characterizations (scanning electron microscopy, X\u2010ray diffraction, and SAED) reveal that the catalyst retains its nanosheet\u2013nanorod morphology and crystalline MoO\n                    <jats:sub>3<\/jats:sub>\n                    phase after repeated use, with only a slight decrease in the crystallinity of the MIL\u2010101(Cr) framework. Mechanistic analyses using X\u2010ray photoelectron spectroscopy, Raman, and temperature\u2010programmed reduction demonstrate that surface oxygen vacancies and Lewis acid sites promote ODS activity, while highly dispersed Ni\u2013MoO\n                    <jats:sub>3<\/jats:sub>\n                    species facilitate H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    activation and Mo\n                    <jats:sup>6+<\/jats:sup>\n                    \/Mo\n                    <jats:sup>5+<\/jats:sup>\n                    redox cycling, leading to efficient generation of reactive oxygen species. The catalyst also exhibits excellent stability, maintaining 98.7% DBT conversion after five cycles. These results demonstrate that the strong Ni\u2013Mo synergistic effect and efficient oxygen activation make Ni\u2013MoO\n                    <jats:sub>3<\/jats:sub>\n                    @MIL\u2010101(Cr) a robust and highly efficient catalyst for deep fuel desulfurization.\n                  <\/jats:p>","DOI":"10.1002\/cplu.70223","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T23:47:11Z","timestamp":1786492031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Ni\u2013MoO\n                    <sub>3<\/sub>\n                    Redox Catalysis in MIL\u2010101(Cr) for Efficient H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>\n                    Activation and Ultra\u2010Deep Desulfurization"],"prefix":"10.1002","volume":"91","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8757-364X","authenticated-orcid":false,"given":"Huan V.","family":"Doan","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering Hanoi University of Mining and Geology  Bac Tu Liem, Hanoi Vietnam"},{"name":"Research School of Chemistry The Australian National University  Canberra Australian Capital Territory Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huong T. T.","family":"Tran","sequence":"additional","affiliation":[{"name":"Faculty of Environment Hanoi University of Mining and Geology  Bac Tu Liem, Hanoi Vietnam"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3385-7188","authenticated-orcid":false,"given":"Duyen T.","family":"Le","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Basic Science Hanoi University of Mining and Geology  Bac Tu Liem, Hanoi Vietnam"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7469-3001","authenticated-orcid":false,"given":"Xuan N.","family":"Pham","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Hanoi University of Mining and Geology  Bac Tu Liem, Hanoi Vietnam"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,11]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2024.07.009"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.125582"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.126032"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1080\/14786451.2024.2321625"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.03.005"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.127729"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.131372"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2023.128982"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cscee.2024.100754"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apt.2017.10.011"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2022.107399"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2022.107480"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8RA00112J"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2020.106685"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2014.04.002"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2018.07.148"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2017.03.052"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8RA02396D"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2023.107980"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2022.134968"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11051-025-06481-1"},{"issue":"1","key":"e_1_2_10_23_1","first-page":"175478","article-title":"Photocatalytic Oxidative Desulfurization of a Model Fuel Using S\u2010Doped TiO2\/BiVO4 Composites: A Combination of Experimental and Theoretical Study","volume":"2024","author":"Baboukani Z. 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