{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T06:59:23Z","timestamp":1790319563290,"version":"4.1.0"},"reference-count":56,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,8,30]],"date-time":"2026-08-30T00:00:00Z","timestamp":1788048000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,30]],"date-time":"2026-08-30T00:00:00Z","timestamp":1788048000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPlusChem"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:p>\n                    Designing green and efficient methods for synthesizing anilines remains a key challenge in synthetic organic chemistry. Hydrogenation of nitro compounds is one of the most significant and widely employed method for producing functionalized anilines. Consequently, designing catalytic systems capable of hydrogenating nitroarenes under environmentally benign and mild reaction conditions remains a challenge. In this regard, a highly efficient CoAl catalyst has been designed for the hydrogenation of nitroarenes to corresponding amines. Various structural, compositional, and morphological characterizations were done to understand the catalyst\u2019s structural and surface properties. The as\u2010synthesized catalyst exhibits excellent activity for the transfer hydrogenation of 1\u2010chloro\u20104\u2010nitrobenzene to 4\u2010chloroaniline, achieving 98% yield at 60\u2009\u00b0C within 1.5\u2009h in ethanol. The developed protocol demonstrated excellent activity for wide range of substituted nitroarenes. Structure\u2010activity relationships of CoAl show that basic sites play a crucial role in the transfer hydrogenation. Furthermore, mechanistic investigations reveal that transfer hydrogenation occurs predominantly via a hydroxylamine\u2010mediated pathway. Moreover, the catalyst maintains good catalytic activity up to four consecutive cycles. This method eliminates the need for high\u2010pressure H\n                    <jats:sub>2<\/jats:sub>\n                    , offering a safe strategy for aromatic amine synthesis. The work demonstrates the potential of earth\u2010abundant, non\u2010noble\u2010metal\u2010based heterogeneous catalysts for hydrogenation reactions under environmentally benign conditions.\n                  <\/jats:p>","DOI":"10.1002\/cplu.70233","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:14:22Z","timestamp":1788135262000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Role of Co\n                    <sup>0<\/sup>\n                    and Lewis Basic Sites for Transfer Hydrogenation of Substituted Nitroarenes by In Situ Hydrogen Generation"],"prefix":"10.1002","volume":"91","author":[{"given":"Anitya","family":"Sharma","sequence":"first","affiliation":[{"name":"School of Chemical Sciences and Advanced Materials Research Center Indian Institute of Technology Mandi  Mandi Himachal Pradesh 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