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The donor and acceptor molecules form mixed D\u2013A\u2013D\u2013A stacks irrespective of the component ratio. The study of electron density topology indicated that each DCNP molecule accepts 0.22\u20130.24 electron charges in the crystal. The intermolecular interaction energy between donor and acceptor molecules ranges from 3.8 to 5.0\u2009kcal\/mol. An evaluation of the dark conductivity of the (cHexDDP\u2022DCNP) sample showed an increase in current by ~5 orders of magnitude upon raising the temperature from 233 to 283\u2009K. 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