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Bidentate diphosphanes were used as chiral ligands. The application of monodentate phosphanes capable of self\u2010assembling with the metal was likewise tested. In the substitution reaction with dimethyl malonate, enantioselectivities up to 98\u2009% were achieved. In the amination reaction, the chiral product was obtained with up to 83\u2009%<\/jats:italic> ee<jats:italic>. The results confirm that these \u201cgreen solvents\u201d can be advantageously used for this catalytic transformation as an alternative to those solvents usually employed which run some risk of being harmful to the environment.<\/jats:italic><\/jats:p>","DOI":"10.1002\/cssc.200700142","type":"journal-article","created":{"date-parts":[[2008,2,20]],"date-time":"2008-02-20T12:04:45Z","timestamp":1203509085000},"page":"249-253","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":106,"title":["Organic Carbonates as Alternative Solvents for Palladium\u2010Catalyzed Substitution Reactions"],"prefix":"10.1002","volume":"1","author":[{"given":"Benjamin","family":"Sch\u00e4ffner","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jens","family":"Holz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey\u2005P.","family":"Verevkin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Armin","family":"B\u00f6rner","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2008,3,17]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200700405"},{"key":"e_1_2_6_2_2","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500368"},{"key":"e_1_2_6_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500368"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20021115)114:22<4350::AID-ANGE4350>3.0.CO;2-0"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20021115)41:22<4176::AID-ANIE4176>3.0.CO;2-U"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9903048"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020039h"},{"key":"e_1_2_6_8_2","unstructured":"\u00a0"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00039a007"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200461432"},{"key":"e_1_2_6_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200461432"},{"key":"e_1_2_6_11_2","unstructured":"\u00a0"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050992x"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200602761"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602761"},{"key":"e_1_2_6_14_2","first-page":"1","volume":"50","author":"Farina V.","year":"1997","journal-title":"Org. 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