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One example is the telomerization of butadiene with glycerol which provides an atom\u2010economic route to amphiphilic molecules. The reaction is catalyzed by homogeneous palladium catalysts which necessitates efficient catalyst recycling. By employing an aqueous biphasic system, an increased selectivity towards the desired mono\u2010ethers was observed in the telomerization reaction. The performance of the reaction and separation and recycling of the catalyst were optimized by the addition of organic solvents as well as cyclodextrins. By adding cyclodextrins, the conversion of glycerol could be increased and the leaching of palladium could be reduced. Leaching of palladium into the organic phase could be lowered also by using 2\u2010octanol or 2\u2010propanol as additional solvents. Furthermore, the catalyst system could be stabilized by adding nitriles or phosphonium salts, and radical polymerization, which leads to fouling, could be inhibited successfully.<\/jats:italic><\/jats:p>","DOI":"10.1002\/cssc.200800197","type":"journal-article","created":{"date-parts":[[2008,12,20]],"date-time":"2008-12-20T09:34:17Z","timestamp":1229765657000},"page":"71-76","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":67,"title":["Telomerization of Butadiene with Glycerol: Reaction Control through Process Engineering, Solvents, and Additives"],"prefix":"10.1002","volume":"2","author":[{"given":"Arno","family":"Behr","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julia","family":"Leschinski","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Colin","family":"Awungacha","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suzana","family":"Simic","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tanja","family":"Knoth","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2009,1,20]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/B710561D"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604694"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604694"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/B707343G"},{"key":"e_1_2_6_4_2","unstructured":"B.Fabry B.Gruber (Henkel) DE4020973 1992."},{"key":"e_1_2_6_5_2","unstructured":"B.Gruber U.Eicken (Henkel) DE4129528 1993."},{"key":"e_1_2_6_6_2","unstructured":"K.Hill U.Mahler (Henkel) WO9202284A1 1992."},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800858"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800792"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/b300138p"},{"key":"e_1_2_6_10_2","volume-title":"Technische Chemie","author":"Baerns M.","year":"2006"},{"key":"e_1_2_6_11_2","volume-title":"Angewandte Homogene Katalyse","author":"Behr A.","year":"2008"},{"key":"e_1_2_6_12_2","first-page":"114","volume-title":"Multiphase Homogeneous Catalysis","author":"Behr A.","year":"2005"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200303087"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(02)00599-X"},{"key":"e_1_2_6_15_2","unstructured":"J. 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