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It is found that the Rh\/SiO<jats:sub>2<\/jats:sub> catalysts modified with ReO<\/jats:italic><jats:sub>x<\/jats:sub> <jats:italic>species exhibited high activity and selectivity in the hydrogenolysis of 1,2\u2010propanediol to propanols with low selectivity to degradation products and high stability. The optimized Rh\uf8ffReO<\/jats:italic><jats:sub>x<\/jats:sub><jats:italic>\/SiO<jats:sub>2<\/jats:sub> (Re\/Rh=0.5) catalyst gave high yields of 1\u2010propanol (66\u2009%) and propanols (1\u2010propanol +2\u2010propanol) (85\u2009%) in the hydrogenolysis of 1,2\u2010propanediol. In addition, the catalyst was applicable to the one\u2010pot conversion of glycerol to propanols. The structure of Rh metal particles with attached ReO<\/jats:italic><jats:sub>x<\/jats:sub> <jats:italic>clusters is suggested from the catalyst characterization. It is proposed that 1,2\u2010propanediol hydrogenolysis proceeds by the hydrogenolysis of the alkoxide species on Re with hydrogen species on the Rh metal surface.<\/jats:italic><\/jats:p>","DOI":"10.1002\/cssc.201000040","type":"journal-article","created":{"date-parts":[[2010,5,6]],"date-time":"2010-05-06T14:19:45Z","timestamp":1273155585000},"page":"728-736","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":133,"title":["Hydrogenolysis of 1,2\u2010Propanediol for the Production of Biopropanols from Glycerol"],"prefix":"10.1002","volume":"3","author":[{"given":"Yasushi","family":"Amada","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuichi","family":"Koso","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoshinao","family":"Nakagawa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keiichi","family":"Tomishige","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,6,11]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050989d"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b615413a"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/B608007C"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2009.02.004"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/B707343G"},{"key":"e_1_2_6_7_2","unstructured":"A.\u2005E. 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