{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T20:55:40Z","timestamp":1784321740609,"version":"3.55.0"},"reference-count":34,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2010,9,27]],"date-time":"2010-09-27T00:00:00Z","timestamp":1285545600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2011,2,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The effect of metal doping (i.e., with Cr, Fe, Ni, Cu, Zn, Ag and Sn) on the crystal structure of hydrothermally synthesized Mn<jats:sub>1\u2212<jats:italic>x<\/jats:italic><\/jats:sub>Cd<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>S (where <jats:italic>x<\/jats:italic>\u22480.1) is studied with the aim of enhancing photocatalytic activity. In contrast to the low\u2010crystalline, undoped solid solution Mn<jats:sub>1\u2212<jats:italic>x<\/jats:italic><\/jats:sub>Cd<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>S, Ni doping yields a well\u2010crystallized wurtzite\u2010type Mn\u2010Cd\u2010S solid solution, which precipitates as planar hexagonal facets of several hundred nanometers in size, together with much larger grains of \u03b1\u2010MnS (&gt;10\u2005\u03bcm). By removing inactive \u03b1\u2010MnS through sedimentation, a single phase with composition of Ni<jats:sub>0.01<\/jats:sub>Mn<jats:sub>0.56<\/jats:sub>Cd<jats:sub>0.43<\/jats:sub>S is obtained successfully. The Ni doping achieved a threefold higher photocatalytic activity for H<jats:sub>2<\/jats:sub> evolution from a 0.1\u2009<jats:sc>M<\/jats:sc> Na<jats:sub>2<\/jats:sub>S\/0.5\u2009<jats:sc>M<\/jats:sc> Na<jats:sub>2<\/jats:sub>SO<jats:sub>3<\/jats:sub> solution under visible\u2010light irradiation (<jats:italic>\u03bb<\/jats:italic>\u2265420\u2005nm). The apparent quantum yield of 1\u2005wt\u2009% Pt\u2010loaded Ni<jats:sub>0.01<\/jats:sub>Mn<jats:sub>0.56<\/jats:sub>Cd<jats:sub>0.43<\/jats:sub>S measured at <jats:italic>\u03bb<\/jats:italic>=420\u2005nm reached 25\u2009%. The enhanced photocatalytic activity is most likely the result of a decreased concentration of defects, responsible for electron\u2013hole recombination, in the active solid\u2010solution phase and a slightly higher bandgap energy (2.4\u2005eV).<\/jats:p>","DOI":"10.1002\/cssc.201000166","type":"journal-article","created":{"date-parts":[[2010,9,27]],"date-time":"2010-09-27T08:21:55Z","timestamp":1285575715000},"page":"269-273","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":61,"title":["Hydrothermal Synthesis of a Doped Mn\u2010Cd\u2010S Solid Solution as a Visible\u2010Light\u2010Driven Photocatalyst for H<sub>2<\/sub> Evolution"],"prefix":"10.1002","volume":"4","author":[{"given":"Keita","family":"Ikeue","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Satoshi","family":"Shiiba","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masato","family":"Machida","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,9,27]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.73.1307"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1023480507710"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac200779111917"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2004.1534"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm7024203"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00375a006"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/j150659a025"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp076566s"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp8037279"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100277a024"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100333a029"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1019067025917"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/b003297m"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp8059008"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp044722e"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja048296m"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500314"},{"key":"e_1_2_6_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500314"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/b204259b"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0269643"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/b309935k"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/B407892F"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2005.05.012"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1038\/440295a"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2007.558"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2007.03.017"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2006.07.052"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2008.09.024"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm9026013"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.48.6111"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0038-1098(01)00119-3"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.341700"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0368-2048(96)80033-8"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.41.5969"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201000166","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201000166","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T17:24:35Z","timestamp":1760376275000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201000166"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,9,27]]},"references-count":34,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2011,2,18]]}},"alternative-id":["10.1002\/cssc.201000166"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201000166","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,9,27]]},"assertion":[{"value":"2010-06-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication 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