{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T14:42:59Z","timestamp":1791297779111,"version":"4.1.0"},"reference-count":44,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2012,2,28]],"date-time":"2012-02-28T00:00:00Z","timestamp":1330387200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2012,3,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Fe oxide nanoparticles show enhanced electrocatalytic performance in the reduction of CO<jats:sub>2<\/jats:sub> to isopropanol when deposited on an <jats:italic>N<\/jats:italic>\u2010functionalized carbon nanotube (CNT) support rather than on a pristine or oxidized CNT support. XRD and high\u2010resolution TEM were used to investigate the nanostructure of the electrocatalysts, and CO<jats:sub>2<\/jats:sub> adsorptive microcalorimetry was used to study the chemical nature of the interaction of CO<jats:sub>2<\/jats:sub> with the surface sites. Although the particles always present the same Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> phase, their structural anisotropy and size inhomogeneity are consequences of the preparation method of the carbon surface. Two types of chemisorption sites have been determined by using microcalorimetry: irreversible sites (280\u2005kJ\u2009mol<jats:sup>\u22121<\/jats:sup>) at the uncoordinated sites of the facets and reversible sites (120\u2005kJ\u2009mol<jats:sup>\u22121<\/jats:sup>) at the hydrated oxide surface of the small nanoparticles. <jats:italic>N<\/jats:italic>\u2010Functionalization of the carbon support is advantageous, as it causes the formation of small nanoparticles, which are highly populated by reversible chemisorbing sites. These characteristic features correlate with a higher electrocatalytic performance.<\/jats:p>","DOI":"10.1002\/cssc.201100641","type":"journal-article","created":{"date-parts":[[2012,2,28]],"date-time":"2012-02-28T11:53:39Z","timestamp":1330430019000},"page":"577-586","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":52,"title":["New Insights from Microcalorimetry on the FeO<sub><i>x<\/i><\/sub>\/CNT\u2010Based Electrocatalysts Active in the Conversion of CO<sub>2<\/sub> to Fuels"],"prefix":"10.1002","volume":"5","author":[{"given":"Rosa","family":"Arrigo","sequence":"first","affiliation":[{"name":"Fritz-Haber-Institut der Max-Planck Gesellschaft Abteilung Anorganische Chemie  Faradayweg 4\u20136 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred E.","family":"Schuster","sequence":"additional","affiliation":[{"name":"Fritz-Haber-Institut der Max-Planck Gesellschaft Abteilung Anorganische Chemie  Faradayweg 4\u20136 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sabine","family":"Wrabetz","sequence":"additional","affiliation":[{"name":"Fritz-Haber-Institut der Max-Planck Gesellschaft Abteilung Anorganische Chemie  Faradayweg 4\u20136 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank","family":"Girgsdies","sequence":"additional","affiliation":[{"name":"Fritz-Haber-Institut der Max-Planck Gesellschaft Abteilung Anorganische Chemie  Faradayweg 4\u20136 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean\u2010Philippe","family":"Tessonnier","sequence":"additional","affiliation":[{"name":"Fritz-Haber-Institut der Max-Planck Gesellschaft Abteilung Anorganische Chemie  Faradayweg 4\u20136 14195 Berlin Germany"},{"name":"Department of Chemical Engineering University of Delaware  150 Academy Street Newark DE 19716 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gabriele","family":"Centi","sequence":"additional","affiliation":[{"name":"Department of Industrial Chemistry and Materials Engineering University of Messina  V.le F. Stagno d'Alcontres, 31 98166 Messina Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siglinda","family":"Perathoner","sequence":"additional","affiliation":[{"name":"Department of Industrial Chemistry and Materials Engineering University of Messina  V.le F. Stagno d'Alcontres, 31 98166 Messina Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dang Sheng","family":"Su","sequence":"additional","affiliation":[{"name":"Fritz-Haber-Institut der Max-Planck Gesellschaft Abteilung Anorganische Chemie  Faradayweg 4\u20136 14195 Berlin Germany"},{"name":"Shenyang National Laboratory for Materials Science, Institute of Metal Research Chinese Academy of Sciences  72 Wenhua Road 110016 Shenyang PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert","family":"Schl\u00f6gl","sequence":"additional","affiliation":[{"name":"Fritz-Haber-Institut der Max-Planck Gesellschaft Abteilung Anorganische Chemie  Faradayweg 4\u20136 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2012,2,28]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200900182"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100084"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470463772"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900275"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0039-6028(01)01583-7"},{"key":"e_1_2_7_6_1","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1007\/978-1-4615-3040-4","volume-title":"Surface Electrochemistry: A Molecular Level Approach","author":">Bockris J. O. M.","year":"1993"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja910169v"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2009.11.018"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200900289"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100473"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2009.07.075"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz1012627"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.3561636"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/b615275a"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-009-9245-x"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2008.11.001"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/b925470f"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2009.07.080"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2009.02.032"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(01)00459-X"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2005.03.029"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8008192"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/b916150c"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2130890"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja072574a"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02436821"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/la9700228"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/0025-5416(67)90030-4"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1088\/0957-4484\/18\/25\/255603"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0921-5093(00)00717-6"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/b304532n"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1006\/jcis.1998.5899"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040-6031(92)87011-X"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(90)90391-K"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01171565"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0360-0564(08)60007-3"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100379a041"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1006\/jcis.1997.5128"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-6031(97)00196-2"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/0390-6035(80)90044-9"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9517(84)90308-7"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/ghg3.3"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100084a023"},{"key":"e_1_2_7_44_1","volume-title":"International Union of Crystallography","author":"Balzar D.","year":"1999"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201100641","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201100641","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.201100641","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201100641","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T17:46:43Z","timestamp":1760377603000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201100641"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,2,28]]},"references-count":44,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2012,3,12]]}},"alternative-id":["10.1002\/cssc.201100641"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201100641","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2012,2,28]]},"assertion":[{"value":"2011-10-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2012-02-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}