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In this report, the solvent effects on the hydrogenolysis of diphenyl ether and lignin with Raney Ni are addressed. The Lewis basicity of the solvent very much affects the catalytic activity, so Raney Ni in nonbasic solvents is an extremely active catalyst for hydrogenolysis and hydrogenation. In basic solvents, however, Raney Ni is a less active, but much more selective catalyst for hydrogenolysis while preserving the aromatic products. With regard to the reactions with lignin, assessing the complexity of the product mixtures by two\u2010dimensional GC\u00d7GC\u2013MS revealed solvent effects on the product distribution. Reaction in methylcyclohexane resulted in cyclic alcohols and cyclic alkanes, whereas reaction in 2\u2010propanol led to cyclic alcohols, cyclic ketones, and unsaturated products. The hydrogenolysis of lignin in methanol, however, produced mostly phenols. Overall, these results demonstrate that the solvent plays a key role in directing the selectivity and, thus, it must be taken into consideration in the design of catalytic systems for conversion of lignin by hydrogenolysis of C\uf8ffO ether bonds.<\/jats:p>","DOI":"10.1002\/cssc.201200040","type":"journal-article","created":{"date-parts":[[2012,5,1]],"date-time":"2012-05-01T23:21:26Z","timestamp":1335914486000},"page":"1455-1466","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":395,"title":["Solvent Effects on the Hydrogenolysis of Diphenyl Ether with Raney Nickel and their Implications for the Conversion of Lignin"],"prefix":"10.1002","volume":"5","author":[{"given":"Xingyu","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roberto","family":"Rinaldi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2012,4,30]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900354u"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201000157"},{"key":"e_1_2_6_4_2","volume-title":"Wood: Chemistry Ultrastructure Reactions","author":"Fengel D.","year":"1984"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","unstructured":"J.\u2005E. 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