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If direct acetalization of HMF with <jats:italic>n<\/jats:italic>\u2010octanol is performed in the presence of strong acids (homogeneous and heterogeneous catalysts), an increase in etherification versus acetalization occurs. Beta zeolite catalyzes both reactions. However, if the acidity of a zeolite (Beta) was controlled by partial exchange of H<jats:sup>+<\/jats:sup> with Na<jats:sup>+<\/jats:sup>, the dioctyl acetal of HMF can be achieved in 95\u2009% yield by transacetalization. It is possible to achieve a high yield in a very short reaction time through a two\u2010step one\u2010pot process, which includes the synthesis of the dimethyl acetal of HMF followed by transacetalization with <jats:italic>n<\/jats:italic>\u2010octanol. The one\u2010pot process could be extended to other alcohols that contain 6\u201312 carbon atoms to afford 87\u201398\u2009% yield of the corresponding dialkyl acetal with a selectivity higher than 96\u2009%. The optimized catalyst with an adequate Na content (1.5NaBeta) could be recycled without loss of activity or selectivity.<\/jats:p>","DOI":"10.1002\/cssc.201200513","type":"journal-article","created":{"date-parts":[[2013,1,9]],"date-time":"2013-01-09T16:42:13Z","timestamp":1357749733000},"page":"123-131","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":64,"title":["From Biomass to Chemicals: Synthesis of Precursors of Biodegradable Surfactants from 5\u2010Hydroxymethylfurfural"],"prefix":"10.1002","volume":"6","author":[{"given":"K. 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