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This waste is composed of Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> (60.7\u2009%), SiO<jats:sub>2<\/jats:sub> (29.1\u2009%), and Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> (3.9\u2009%) as the main components. The high presence of iron oxides was used to develop photocatalytic properties through their thermal transformation into \u03b1\u2010Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>. The new product, SOW\u2010T, exhibited a good behavior towards the photochemical degradation of organic dyes. The preparation of advanced photocatalytic materials that exhibit self\u2010cleaning and depolluting properties was possible by the inclusion of SOW\u2010T and TiO<jats:sub>2<\/jats:sub> in a cement\u2010based mortar. The synergy observed between both materials enhanced their photocatalytic action. 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