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The etherification step was optimized using aluminosilicates as acid catalysts with different pore topologies (H\u2010Beta, HY, Mordenite, ZSM\u20105, ITQ\u20102, and MCM\u201041), different active sites (Bronsted or Lewis) and different adsorption properties. It was shown that highly hydrophobic defect\u2010free H\u2010Beta zeolites with Si\/Al ratios higher than 25 are excellent acid catalysts to perform the selective etherification of HMF with fatty alcohols, avoiding the competitive self\u2010etherification of HMF. Moreover, the 5\u2010alkoxymethylfurfural derivatives obtained can be selectively oxidized to the corresponding furoic salts in excellent yield using Au\/CeO<jats:sub>2<\/jats:sub> as catalyst and air as oxidant, at moderated temperatures. Both H\u2010Beta zeolite and Au\/CeO<jats:sub>2<\/jats:sub> could be reused several times without loss of activity.<\/jats:p>","DOI":"10.1002\/cssc.201300531","type":"journal-article","created":{"date-parts":[[2013,10,8]],"date-time":"2013-10-08T08:17:31Z","timestamp":1381220251000},"page":"210-220","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":80,"title":["Biomass\u2010Derived Chemicals: Synthesis of Biodegradable Surfactant Ether Molecules from Hydroxymethylfurfural"],"prefix":"10.1002","volume":"7","author":[{"given":"Karen S.","family":"Arias","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria J.","family":"Climent","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Avelino","family":"Corma","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sara","family":"Iborra","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2013,9,18]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature05923"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201007508"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201007508"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0gc00639d"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2012.05.002"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0gc00401d"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/cite.201200203"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2GC36536G"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200900059"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201200513"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470686607"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15217C"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11743-012-1382-8"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11743-012-1408-2"},{"key":"e_1_2_6_14_2","unstructured":"R. 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