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The remarkable activity of Pd\/Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> in both transfer hydrogenation\/hydrogenolysis is attributed to a strong metal\u2013support interaction. Selectivity towards hydrogenation, hydrogenolysis, decarbonylation, and ring\u2010hydrogenation products is shown to strongly depend on the Pd loading. A significant enhancement in yield to 62\u2009%, of 2\u2010methylfuran and 2\u2010methyltetrahydrofuran was observed under continuous flow conditions.<\/jats:p>","DOI":"10.1002\/cssc.201300774","type":"journal-article","created":{"date-parts":[[2013,11,13]],"date-time":"2013-11-13T15:37:56Z","timestamp":1384357076000},"page":"268-275","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":333,"title":["Catalytic Transfer Hydrogenation\/Hydrogenolysis for Reductive Upgrading of Furfural and 5\u2010(Hydroxymethyl)furfural"],"prefix":"10.1002","volume":"7","author":[{"given":"David","family":"Scholz","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christof","family":"Aellig","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ive","family":"Hermans","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2013,11,13]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ra21811a"},{"key":"e_1_2_6_2_2","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201000375"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201000181"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201200279"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2012.05.043"},{"key":"e_1_2_6_7_2","unstructured":"\u00a0"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature05923"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.3987\/COM-08-S(F)81"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/c004343e"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2GC36536G"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b812886c"},{"key":"e_1_2_6_13_2","unstructured":"\u00a0"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-011-0581-7"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2010.10.005"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.02.006"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.09.005"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1019090520407"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2005.10.003"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-010-9568-7"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100648"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo01102a002"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie50459a034"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)00421-5"},{"key":"e_1_2_6_25_2","unstructured":"\u00a0"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs300785r"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2006.02.055"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2008.11.008"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2006.12.016"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201002267"},{"key":"e_1_2_6_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201002267"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201300288"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(01)00700-1"},{"key":"e_1_2_6_33_2","unstructured":"\u00a0"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2012.03.067"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.06.020"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/b915745j"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1006\/jcat.1997.1683"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2010.02.021"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(02)00248-1"},{"key":"e_1_2_6_40_2","volume-title":"Handbook of X\u2010Ray Photoelectron Spectroscopy","author":"Moulder J.","year":"1992"},{"key":"e_1_2_6_41_2","unstructured":"D. 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