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Both of the redox couples exhibit distinct redox potentials and attractive electrochemical characteristics. The UV\/Vis absorption spectra of JC\u2010IL shows a low\u2010intensity peak compared to the strong absorption of I<jats:sub>2<\/jats:sub> in the wavelength region of 350\u2013500\u2005nm. The high open\u2010circuit voltage of DSSCs with JC\u2010IL is over 850\u2005mV, which is approximately 150\u2005mV higher than that of the DSSCs with a standard iodide electrolyte. The dramatic increase in the standard heterogeneous electron\u2010transfer rate constant leads to an increase in the short\u2010circuit current for JC\u2010IL compared to that of 2,2,6,6\u2010tetramethylpiperidin\u2010<jats:italic>N<\/jats:italic>\u2010oxyl (TEMPO). DSSCs with the JC\u2010IL electrolyte show promising cell efficiencies if coupled with dyes CR147 (8.12\u2009%) or D149 (6.76\u2009%). The efficiencies of the DSSCs based on the JC\u2010IL electrolyte are higher than those of DSSCs based on either TEMPO electrolyte or standard iodide electrolyte alone.<\/jats:p>","DOI":"10.1002\/cssc.201301015","type":"journal-article","created":{"date-parts":[[2013,12,12]],"date-time":"2013-12-12T08:47:13Z","timestamp":1386838033000},"page":"146-153","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Ionic Liquid with a Dual\u2010Redox Couple for Efficient Dye\u2010Sensitized Solar Cells"],"prefix":"10.1002","volume":"7","author":[{"given":"Te\u2010Chun","family":"Chu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ryan Yeh\u2010Yung","family":"Lin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chuan\u2010Pei","family":"Lee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chih\u2010Yu","family":"Hsu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pei\u2010Chieh","family":"Shih","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ray","family":"Lin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sie\u2010Rong","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shin\u2010Sheng","family":"Sun","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jiann T.","family":"Lin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"R.","family":"Vittal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kuo\u2010Chuan","family":"Ho","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2013,12,12]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar980112j"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/353737a0"},{"key":"e_1_2_6_4_2","unstructured":"\u00a0"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee22095d"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1jm10598a"},{"key":"e_1_2_6_7_2","unstructured":"\u00a0"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar900138m"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm200651e"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1209688"},{"key":"e_1_2_6_11_2","unstructured":"\u00a0"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm400796u"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201200973"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp2025736"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1088869"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja305897k"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1655"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp100957p"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.966"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee23081j"},{"key":"e_1_2_6_21_2","unstructured":"\u00a0"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201003740"},{"key":"e_1_2_6_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201003740"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201300238"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2030933"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200701041"},{"key":"e_1_2_6_26_2","unstructured":"\u00a0"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201205036"},{"key":"e_1_2_6_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205036"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2010.464"},{"key":"e_1_2_6_29_2","unstructured":"\u00a0"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ta00719c"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja062087f"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ra20310c"},{"key":"e_1_2_6_33_2","unstructured":"\u00a0"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm203790z"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja401827w"},{"key":"e_1_2_6_36_2","unstructured":"\u00a0"},{"key":"e_1_2_6_37_2","first-page":"607","volume":"4","author":"Wu X. 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