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We design and synthesize a unique four\u2010layer yolk\u2013shell tin\u2013carbon (Sn\u2013C) nanotube array to address this problem. The shape and size of the exterior Sn\u2005nanotube@carbon core\u2013shell layer, the encapsulated interior Sn nanowire@carbon nanotube core\u2013shell layer, and the filling level of each layer can be all controlled by adjusting the experimental conditions. Such a nanostructure has not been reported for any metal or metal oxide\u2010based material. Owing to the special design of the electrode structure, the four\u2010layer hierarchical structure demonstrates excellent Li\u2010ion storage properties in terms of high capacity, long cycle life, and high rate performance.<\/jats:p>","DOI":"10.1002\/cssc.201301198","type":"journal-article","created":{"date-parts":[[2014,3,19]],"date-time":"2014-03-19T22:45:07Z","timestamp":1395269107000},"page":"1407-1414","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Four\u2010Layer Tin\u2013Carbon Nanotube Yolk\u2013Shell Materials for High\u2010Performance Lithium\u2010Ion 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