{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,6]],"date-time":"2025-12-06T17:00:49Z","timestamp":1765040449846,"version":"build-2065373602"},"reference-count":33,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2014,3,26]],"date-time":"2014-03-26T00:00:00Z","timestamp":1395792000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2014,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis of organized mesoporous SnO<jats:sub>2<\/jats:sub> films with high porosity, larger pores, and good interconnectivity, obtained by sol\u2013gel templating with an amphiphilic graft copolymer, poly(vinyl chloride)\u2010<jats:italic>graft<\/jats:italic>\u2010poly(oxyethylene methacrylate), is reported. An improved performance of dye\u2010sensitized solar cells (DSSCs) is demonstrated by the introduction of a 400\u2005nm thick organized mesoporous SnO<jats:sub>2<\/jats:sub> interfacial (om\u2010SnO<jats:sub>2<\/jats:sub> IF) layer between nanocrystalline TiO<jats:sub>2<\/jats:sub> (nc\u2010TiO<jats:sub>2<\/jats:sub>) and a fluorine\u2010doped tin oxide substrate. To elucidate the improved efficiency, the structural, optical, and electrochemical properties of the devices were characterized by SEM, UV\/Vis spectroscopy, noncontact 3D surface profilometry, intensity\u2010modulated photocurrent\/voltage spectroscopy, incident photon\u2010to\u2010electron conversion efficiency, and electrochemical impedance spectroscopy measurements. The energy\u2010conversion efficiency of the solid polymerized ionic liquid based DSSC fabricated with the om\u2010SnO<jats:sub>2<\/jats:sub> IF\/nc\u2010TiO<jats:sub>2<\/jats:sub> photoanode reached 5.9\u2009% at 100\u2005mW\u2009cm<jats:sup>\u22122<\/jats:sup>; this is higher than those of neat nc\u2010TiO<jats:sub>2<\/jats:sub> (3.5\u2009%) and organized mesoporous TiO<jats:sub>2<\/jats:sub> interfacial\/nc\u2010TiO<jats:sub>2<\/jats:sub> layer (5.4\u2009%) photoanodes. The improved efficiency is attributed to the antireflective property, cascadal energy band gap, good interconnectivity, and high electrical conductivity of the om\u2010SnO<jats:sub>2<\/jats:sub> IF layer, which results in enhanced light harvesting, increased electron transport, reduced charge recombination, and decreased interfacial\/internal resistance.<\/jats:p>","DOI":"10.1002\/cssc.201301215","type":"journal-article","created":{"date-parts":[[2014,3,26]],"date-time":"2014-03-26T16:36:28Z","timestamp":1395851788000},"page":"2037-2047","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Multifunctional Organized Mesoporous Tin Oxide Films Templated by Graft Copolymers for Dye\u2010Sensitized Solar Cells"],"prefix":"10.1002","volume":"7","author":[{"given":"Jung Tae","family":"Park","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sung 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