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Herein we describe a robust artificial photocatalyst, nickel\u2010hybrid CdS quantum dots (Ni<jats:sub>h<\/jats:sub>\u2010CdS QDs) made in\u2005situ from nickel salts and CdS QDs stabilized by 3\u2010mercaptopropionic acid, for visible\u2010light\u2010driven H<jats:sub>2<\/jats:sub> evolution from glycerol and water. With visible light irradiation for 20\u2005h, 403.2\u2005\u03bcmol of H<jats:sub>2<\/jats:sub> was obtained with a high H<jats:sub>2<\/jats:sub> evolution rate of approximately 74.6\u2005\u03bcmol\u2009h<jats:sup>\u22121<\/jats:sup>\u2009mg<jats:sup>\u22121<\/jats:sup> and a high turnover number of 38\u2009405 compared to MPA\u2010CdS QDs (mercaptopropionic\u2010acid\u2010stabilized CdS quantum dots). Compared to CdTe QDs and CdSe QDs, the modified CdS QDs show the greatest affinity toward Ni<jats:sup>2+<\/jats:sup> ions and the highest activity for H<jats:sub>2<\/jats:sub> evolution. X\u2010ray photoelectron spectroscopy (XPS), inductively\u2010coupled plasma atomic emission spectrometry (ICP\u2010AES), and photophysical studies reveal the chemical nature of the Ni<jats:sub>h<\/jats:sub>\u2010CdS QDs. Electron paramagnetic resonance (EPR) and terephthalate fluorescence measurements clearly demonstrate water splitting to generate <jats:bold>\u22c5<\/jats:bold>OH radicals. The detection of DMPO\u2010H and DMPO\u2010C radicals adduct in EPR also indicate that <jats:bold>\u22c5<\/jats:bold>H radicals and <jats:bold>\u22c5<\/jats:bold>C radicals are the active species in the catalytic cycle.<\/jats:p>","DOI":"10.1002\/cssc.201400028","type":"journal-article","created":{"date-parts":[[2014,4,1]],"date-time":"2014-04-01T06:53:51Z","timestamp":1396335231000},"page":"1468-1475","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":106,"title":["Photocatalytic Hydrogen Evolution from Glycerol and Water over Nickel\u2010Hybrid Cadmium Sulfide Quantum Dots under Visible\u2010Light 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