{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T13:20:47Z","timestamp":1788268847939,"version":"build-2803163510"},"reference-count":77,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2014,10,24]],"date-time":"2014-10-24T00:00:00Z","timestamp":1414108800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2015,1]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Organic nitriles constitute key precursors and central intermediates in organic synthesis. In addition, nitriles represent a versatile motif found in numerous medicinally and biologically important compounds. Generally, these nitriles are synthesized by traditional cyanation procedures using toxic cyanides. Herein, we report the selective and environmentally benign oxidative conversion of primary amines for the synthesis of structurally diverse aromatic, aliphatic and heterocyclic nitriles using a reusable \u201cnanorust\u201d (nanoscale Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>)\u2010based catalysts applying molecular oxygen.<\/jats:p>","DOI":"10.1002\/cssc.201402613","type":"journal-article","created":{"date-parts":[[2014,10,24]],"date-time":"2014-10-24T16:28:45Z","timestamp":1414168125000},"page":"92-96","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":79,"title":["\u201cNanorust\u201d\u2010catalyzed Benign Oxidation of Amines for Selective Synthesis of Nitriles"],"prefix":"10.1002","volume":"8","author":[{"given":"Rajenahally V.","family":"Jagadeesh","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Henrik","family":"Junge","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Beller","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,10,24]]},"reference":[{"key":"e_1_2_4_1_2","unstructured":"\u00a0"},{"key":"e_1_2_4_2_2","volume-title":"Amines: Synthesis Properties, and Application,","author":"Lawrence S. A.","year":"2004"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(01)00813-4"},{"key":"e_1_2_4_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr970343o"},{"key":"e_1_2_4_5_2","unstructured":"For transformations of amines see:"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol302708r"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201001602"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200801265"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201100255"},{"key":"e_1_2_4_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1229712"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201200247"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1547"},{"key":"e_1_2_4_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0650293"},{"key":"e_1_2_4_14_2","unstructured":"For oxidations of amines see:"},{"key":"e_1_2_4_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja411692v"},{"key":"e_1_2_4_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200250779"},{"key":"e_1_2_4_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200250779"},{"key":"e_1_2_4_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304654"},{"key":"e_1_2_4_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201304654"},{"key":"e_1_2_4_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201007056"},{"key":"e_1_2_4_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201007056"},{"key":"e_1_2_4_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201004365"},{"key":"e_1_2_4_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201004365"},{"key":"e_1_2_4_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs300212q"},{"key":"e_1_2_4_21_2","unstructured":"\u00a0"},{"key":"e_1_2_4_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm100762r"},{"key":"e_1_2_4_23_2","volume-title":"Pharmaceutical Substances: Syntheses, Patents, Applications of the Most Relevant APIs, 4th\u2005ed.","author":"Kleemann A.","year":"2001"},{"key":"e_1_2_4_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/a804370a"},{"key":"e_1_2_4_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/nprot.2007.280"},{"key":"e_1_2_4_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201117"},{"key":"e_1_2_4_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201201117"},{"key":"e_1_2_4_27_2","volume-title":"Chemistry of the Cyano Group","author":"Rappoport Z.","year":"1970"},{"key":"e_1_2_4_28_2","volume-title":"Comprehensive Organic Transformations: A Guide to Functional Group Preparations","author":"Larock R. C.","year":"1989"},{"key":"e_1_2_4_29_2","unstructured":"For cyanation see:"},{"key":"e_1_2_4_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15004a"},{"key":"e_1_2_4_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200390210"},{"key":"e_1_2_4_32_2","first-page":"1946","volume":"18","author":"Sandmeyer T.","year":"1885","journal-title":"Chem. Ber."},{"key":"e_1_2_4_33_2","unstructured":"For ammoxidation see:"},{"key":"e_1_2_4_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201000173"},{"key":"e_1_2_4_35_2","volume-title":"Metal Oxide Catalysis","author":"Cavani F.","year":"2009"},{"key":"e_1_2_4_36_2","volume-title":"Handbook of Heterogeneous Catalysis","author":"Grasselli R. K.","year":"2008"},{"key":"e_1_2_4_37_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(99)00309-0"},{"key":"e_1_2_4_38_2","unstructured":"For ruthenium\u2010catalyzed oxidations of amines to nitrile see:"},{"key":"e_1_2_4_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/b715627h"},{"key":"e_1_2_4_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2010.04.009"},{"key":"e_1_2_4_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201103913"},{"key":"e_1_2_4_42_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cy00209h"},{"key":"e_1_2_4_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja409223a"},{"key":"e_1_2_4_44_2","unstructured":"For copper\u2010catalyzed oxidations of primary amines to nitriles see:"},{"key":"e_1_2_4_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs400360e"},{"key":"e_1_2_4_46_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1989-27286"},{"key":"e_1_2_4_47_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)89050-4"},{"key":"e_1_2_4_48_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.76.2399"},{"key":"e_1_2_4_49_2","unstructured":"\u00a0"},{"key":"e_1_2_4_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527623273"},{"key":"e_1_2_4_51_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.315"},{"key":"e_1_2_4_52_2","volume-title":"Iron Catalysis: Fundamentals and Applications","author":"Plietker B.","year":"2010"},{"key":"e_1_2_4_53_2","unstructured":"For selected Reviews on iron catalysis see:"},{"key":"e_1_2_4_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr040664h"},{"key":"e_1_2_4_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800012"},{"key":"e_1_2_4_55_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800012"},{"key":"e_1_2_4_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar800039x"},{"key":"e_1_2_4_57_2","doi-asserted-by":"publisher","DOI":"10.1039\/b806837m"},{"key":"e_1_2_4_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc05733a"},{"key":"e_1_2_4_59_2","unstructured":"For oxidations using molecular oxygen see"},{"key":"e_1_2_4_60_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1114666"},{"key":"e_1_2_4_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/3527603689"},{"key":"e_1_2_4_62_2","volume-title":"Metal Catalyzed Oxidation of Organic Compounds","author":"Sheldon R. A.","year":"1981"},{"key":"e_1_2_4_63_2","volume-title":"Advances in Oxygenated Processes, Vol.\u20053","author":"Hill C. L.","year":"1998"},{"key":"e_1_2_4_64_2","unstructured":"For iron and cobalt metal oxide\u2010based nanocatalysts see:"},{"key":"e_1_2_4_65_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1242005"},{"key":"e_1_2_4_66_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1645"},{"key":"e_1_2_4_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja403615c"},{"key":"e_1_2_4_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310420"},{"key":"e_1_2_4_68_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310420"},{"key":"e_1_2_4_69_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc13728j"},{"key":"e_1_2_4_70_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5123"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201402613","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201402613","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T08:42:14Z","timestamp":1760344934000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201402613"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,10,24]]},"references-count":77,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2015,1]]}},"alternative-id":["10.1002\/cssc.201402613"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201402613","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,10,24]]},"assertion":[{"value":"2014-07-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2014-10-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}