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Besides, the alkali ions can be added both during the preparation of the catalyst or directly to the solvent mixture to achieve the highest reported yield of methyl lactate (ca. 75\u2009%) from sucrose at 170\u2009\u00b0C in methanol. The beneficial effect of adding alkali to the reaction media applies not only to highly defect\u2010free Sn\u2010Beta prepared through the fluoride route, but also to materials prepared by post\u2010treatment of dealuminated commercial Beta zeolites, as well as ordered mesoporous stannosilicates, in this case Sn\u2010MCM\u201041 and Sn\u2010SBA\u201015. These findings open the door to the possibility of using other preparation methods or different Sn\u2010containing silicates with equally high methyl lactate yields as Sn\u2010Beta.<\/jats:p>","DOI":"10.1002\/cssc.201403057","type":"journal-article","created":{"date-parts":[[2015,1,21]],"date-time":"2015-01-21T09:25:39Z","timestamp":1421832339000},"page":"613-617","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":145,"title":["Tin\u2010containing Silicates: Alkali Salts Improve Methyl Lactate Yield from Sugars"],"prefix":"10.1002","volume":"8","author":[{"given":"S\u00f8ren","family":"Tolborg","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Irantzu","family":"S\u00e1daba","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian M.","family":"Osmundsen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Fristrup","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin S.","family":"Holm","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Esben","family":"Taarning","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,1,21]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1183990"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1002358107"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C004518G"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs2000544"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1098\/rspa.2012.0047"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs500466j"},{"key":"e_1_2_3_8_2","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/35086546"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja012297m"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/B313738D"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2006.11.010"},{"key":"e_1_2_3_13_2","unstructured":"\u00a0"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200900099"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/b921284a"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt52972j"},{"key":"e_1_2_3_17_2","unstructured":"\u00a0"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2gc16202d"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1206708109"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs300474x"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400203v"},{"key":"e_1_2_3_22_2","unstructured":"\u00a0"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2005.1560"},{"key":"e_1_2_3_24_2","doi-asserted-by":"crossref","unstructured":"M. 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