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TiO<jats:sub>2<\/jats:sub> NT arrays with 8\u2005nm thick walls showed higher capacity (\u2248250\u2005mA\u2009h\u2009g<jats:sup>\u22121<\/jats:sup> after the 50th\u2005cycle at a rate of C\/10) than the typical theoretical capacity of bulk TiO<jats:sub>2<\/jats:sub> and a radically improved capacity retention property upon cycling. SnO<jats:sub>2<\/jats:sub> NT arrays with different wall thicknesses (8, 10, 13, and 20\u2005nm) were also fabricated and their electrochemical performances were measured. All of the SnO<jats:sub>2<\/jats:sub> NT arrays showed substantially higher initial irreversible capacity and higher reversible capacity than those of bulk TiO<jats:sub>2<\/jats:sub>. Thinner walls of the SnO<jats:sub>2<\/jats:sub> NTs result in better capacity retention. Heterotubular structures of TiO<jats:sub>2<\/jats:sub> (5\u2005nm)\/SnO<jats:sub>2<\/jats:sub> (10\u2005nm)\/TiO<jats:sub>2<\/jats:sub> (5\u2005nm) were successfully fabricated, and displayed a sufficiently high capacity (\u2248300\u2005mA\u2009h\u2009g<jats:sup>\u22121<\/jats:sup> after 50\u2005cycles) with exceptionally improved cycling performance up to the 50th cycle.<\/jats:p>","DOI":"10.1002\/cssc.201500005","type":"journal-article","created":{"date-parts":[[2015,3,20]],"date-time":"2015-03-20T12:17:02Z","timestamp":1426853822000},"page":"2363-2371","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Nanotubular Heterostructure of Tin Dioxide\/Titanium Dioxide as a Binder\u2010Free Anode in Lithium\u2010Ion 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