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The development of high\u2010rate anode materials is highly desirable for sodium\u2010ion batteries. The optimization of mass transport and electron transfer is crucial in the discovery of electrode materials with good high\u2010rate performances. Herein, we report the synthesis of 3\u2009D interconnected SnO<jats:sub>2<\/jats:sub>\/graphene aerogels with a hierarchically porous structure as anode materials for sodium\u2010ion batteries. The unique 3\u2009D architecture was prepared by a facile in\u2005situ process, during which cross\u2010linked 3\u2009D conductive graphene networks with macro\u2010\/meso\u2010sized hierarchical pores were formed and SnO<jats:sub>2<\/jats:sub> nanoparticles were dispersed uniformly on the graphene surface simultaneously. Such a 3\u2009D functional architecture not only facilitates the electrode\u2013electrolyte interaction but also provides an efficient electron pathway within the graphene networks. When applied as anode materials in sodium\u2010ion batteries, the as\u2010prepared SnO<jats:sub>2<\/jats:sub>\/graphene aerogel exhibited high reversible capacity, improved cycling performance compared to SnO<jats:sub>2<\/jats:sub>, and promising high\u2010rate capability.<\/jats:p>","DOI":"10.1002\/cssc.201500149","type":"journal-article","created":{"date-parts":[[2015,6,16]],"date-time":"2015-06-16T06:39:47Z","timestamp":1434436787000},"page":"2948-2955","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":77,"title":["3D Networked Tin Oxide\/Graphene Aerogel with a Hierarchically Porous Architecture for High\u2010Rate Performance Sodium\u2010Ion 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