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These remarkably soluble BPTI derivatives show strong optical absorption in the range of <jats:italic>\u03bb<\/jats:italic>=300\u2013500\u2005nm and have a high triplet\u2010state energy of 1.67\u2005eV. A cyanophenyl substituent renders BPTI such a strong electron acceptor (<jats:italic>E<\/jats:italic><jats:sub>red<\/jats:sub>=\u22120.11\u2005V vs. the normal hydrogen electrode) that electron\u2010trapping reactions with O<jats:sub>2<\/jats:sub> and H<jats:sub>2<\/jats:sub>O do not occur. The BPTI radical anion on a fluorine\u2010doped tin oxide|TiO<jats:sub>2<\/jats:sub> electrode is persistent up to tens of seconds (<jats:italic>t<\/jats:italic><jats:sub>1\/2<\/jats:sub>=39\u2005s) in air\u2010saturated buffer solution. As a result of favorable packing, theoretical electron mobilities (10<jats:sup>\u22122<\/jats:sup>\u223c10<jats:sup>\u22121<\/jats:sup>\u2005cm<jats:sup>2<\/jats:sup>\u2009V<jats:sup>\u22121<\/jats:sup>\u2009s<jats:sup>\u22121<\/jats:sup>) are high and similar to the experimental values observed for perylene diimide and C<jats:sub>60<\/jats:sub> derivatives. Our studies show the potential of the cyanophenyl\u2010modified BPTI compounds as electron acceptors in devices for artificial photosynthesis in water splitting that are also very promising nonfullerene electron\u2010transport materials for organic solar cells.<\/jats:p>","DOI":"10.1002\/cssc.201500950","type":"journal-article","created":{"date-parts":[[2015,9,23]],"date-time":"2015-09-23T09:10:44Z","timestamp":1442999444000},"page":"3639-3650","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Highly Soluble Benzo[ghi]perylenetriimide Derivatives: Stable and Air\u2010Insensitive Electron Acceptors for Artificial Photosynthesis"],"prefix":"10.1002","volume":"8","author":[{"given":"Hung\u2010Cheng","family":"Chen","sequence":"first","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  P.O. Box 94157 1090 GD Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao\u2010Ping","family":"Hsu","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Academia Sinica  128 Section 2 Academia Road Nankang Taipei 11529 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joost N. H.","family":"Reek","sequence":"additional","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  P.O. Box 94157 1090 GD Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren\u00e9 M.","family":"Williams","sequence":"additional","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  P.O. 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