{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T08:08:44Z","timestamp":1789978124903,"version":"4.0.1"},"reference-count":53,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2016,1,28]],"date-time":"2016-01-28T00:00:00Z","timestamp":1453939200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Danish National Advanced Technology Foundation (Fuel Scale Integrate)"},{"DOI":"10.13039\/501100001732","name":"Danish National Research Foundation","doi-asserted-by":"crossref","award":["DNRF93"],"award-info":[{"award-number":["DNRF93"]}],"id":[{"id":"10.13039\/501100001732","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2016,3,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>TiO<jats:sub>2<\/jats:sub>@SnO<jats:sub>2<\/jats:sub> hybrid nanocomposites were successfully prepared in gram scale using a dual\u2010stage hydrothermal continuous\u2010flow reactor. Temperature and pH in the secondary reactor were found to selectively direct nucleation and growth of the secondary material into either heterogeneous nanocomposites or separate intermixed nanoparticles. At low pH, 2\u2005nm rutile SnO<jats:sub>2<\/jats:sub> nanoparticles were deposited on 9\u2005nm anatase TiO<jats:sub>2<\/jats:sub> particles; the presence of TiO<jats:sub>2<\/jats:sub> was found to suppress formation of larger SnO<jats:sub>2<\/jats:sub> particles. At high pH SnO<jats:sub>2<\/jats:sub> formed separate particles and no deposition on TiO<jats:sub>2<\/jats:sub> was observed. Ball\u2010milling of TiO<jats:sub>2<\/jats:sub> and SnO<jats:sub>2<\/jats:sub> produced no TiO<jats:sub>2<\/jats:sub>@SnO<jats:sub>2<\/jats:sub> composites. This verifies that the composite particles must be formed by nucleation and growth of the secondary precursor on the TiO<jats:sub>2<\/jats:sub>. High concentration of secondary precursor led to formation of TiO<jats:sub>2<\/jats:sub> particles embedded in aggregates of SnO<jats:sub>2<\/jats:sub> nanoparticles. The results demonstrate how nanocomposites may be produced in high yield by green chemistry.<\/jats:p>","DOI":"10.1002\/cssc.201501199","type":"journal-article","created":{"date-parts":[[2016,1,28]],"date-time":"2016-01-28T21:28:52Z","timestamp":1454016532000},"page":"532-539","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Hydrothermal Synthesis of TiO<sub>2<\/sub>@SnO<sub>2<\/sub> Hybrid Nanoparticles in a Continuous\u2010Flow Dual\u2010Stage Reactor"],"prefix":"10.1002","volume":"9","author":[{"given":"Henrik L.","family":"Hellstern","sequence":"first","affiliation":[{"name":"Center for Materials Crystallography Department of Chemistry Aarhus University  Langelangsgade 140 8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Bremholm","sequence":"additional","affiliation":[{"name":"Center for Materials Crystallography Department of Chemistry Aarhus University  Langelangsgade 140 8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aref","family":"Mamakhel","sequence":"additional","affiliation":[{"name":"Center for Materials Crystallography Department of Chemistry Aarhus University  Langelangsgade 140 8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jacob","family":"Becker","sequence":"additional","affiliation":[{"name":"Center for Materials Crystallography Department of Chemistry Aarhus University  Langelangsgade 140 8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo B.","family":"Iversen","sequence":"additional","affiliation":[{"name":"Center for Materials Crystallography Department of Chemistry Aarhus University  Langelangsgade 140 8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,1,28]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100449n"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200900320"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/0925-4005(91)80213-4"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm16328d"},{"key":"e_1_2_6_5_1","first-page":"610","volume":"22","author":"Yan X. 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