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Here, graphene was successfully created from the greenhouse gas CO<jats:sub>2<\/jats:sub> using molten salts. The results showed that CO<jats:sub>2<\/jats:sub> could be effectively fixed by oxygen ions in CaCl<jats:sub>2<\/jats:sub>\u2013NaCl\u2013CaO melts to form carbonate ions, and subsequently electrochemically split into graphene on a stainless steel cathode; O<jats:sub>2<\/jats:sub> gas was produced at the RuO<jats:sub>2<\/jats:sub>\u2013TiO<jats:sub>2<\/jats:sub> inert anode. The formation of graphene in this manner can be ascribed to the catalysis of active Fe, Ni, and Cu atoms at the surface of the cathode and the microexplosion effect through evolution of CO in between graphite layers. This finding may lead to a new generation of proceedures for the synthesis of high value\u2010added products from CO<jats:sub>2<\/jats:sub>, which may also contribute to the establishment of a low\u2010carbon and sustainable world.<\/jats:p>","DOI":"10.1002\/cssc.201501591","type":"journal-article","created":{"date-parts":[[2016,2,12]],"date-time":"2016-02-12T10:15:30Z","timestamp":1455272130000},"page":"588-594","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":127,"title":["Direct Conversion of Greenhouse Gas CO<sub>2<\/sub> into Graphene via Molten Salts Electrolysis"],"prefix":"10.1002","volume":"9","author":[{"given":"Liwen","family":"Hu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing  Beijing 100083 P.R. 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