{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T14:28:23Z","timestamp":1789655303833,"version":"4.0.1"},"reference-count":56,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2016,4,5]],"date-time":"2016-04-05T00:00:00Z","timestamp":1459814400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21403079"],"award-info":[{"award-number":["21403079"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"crossref","award":["2662015PY039"],"award-info":[{"award-number":["2662015PY039"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"crossref","award":["2662015PY210"],"award-info":[{"award-number":["2662015PY210"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Hong Kong Scholars Program","award":["XJ2013005"],"award-info":[{"award-number":["XJ2013005"]}]},{"DOI":"10.13039\/100007567","name":"City University of Hong Kong","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100007567","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2016,5,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Graphene\u2010based ternary composite photocatalysts with genuine heterostructure constituents have attracted extensive attention in photocatalytic hydrogen evolution. Here we report a new graphene\u2010based ternary composite consisting of CdS nanorods grown on hierarchical layered WS<jats:sub>2<\/jats:sub>\/graphene hybrid (WG) as a high\u2010performance photocatalyst for hydrogen evolution under visible light irradiation. The optimal content of layered WG as a co\u2010catalyst in the ternary CdS\/WS<jats:sub>2<\/jats:sub>\/graphene composites was found to be 4.2\u2005wt\u2009%, giving a visible light photocatalytic H<jats:sub>2<\/jats:sub>\u2010production rate of 1842\u2005\u03bcmol\u2009h<jats:sup>\u22121<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup> with an apparent quantum e\ufb03ciency of 21.2\u2009% at 420\u2005nm. This high photocatalytic H<jats:sub>2<\/jats:sub>\u2010production activity is due to the deposition of CdS nanorods on layered WS<jats:sub>2<\/jats:sub>\/graphene sheets, which can efficiently suppress charge recombination, improve interfacial charge transfer, and provide reduction active sites. The proposed mechanism for the enhanced photocatalytic activity of CdS nanorods modified with hierarchical layered WG was further confirmed by transient photocurrent response. This work shows that a noble\u2010metal\u2010free hierarchical layered WS<jats:sub>2<\/jats:sub>\/graphene nanosheets hybrid can be used as an effective co\u2010catalyst for photocatalytic water splitting.<\/jats:p>","DOI":"10.1002\/cssc.201501702","type":"journal-article","created":{"date-parts":[[2016,4,10]],"date-time":"2016-04-10T08:42:29Z","timestamp":1460277749000},"page":"996-1002","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":286,"title":["Hierarchical Layered WS<sub>2<\/sub>\/Graphene\u2010Modified CdS Nanorods for Efficient Photocatalytic Hydrogen Evolution"],"prefix":"10.1002","volume":"9","author":[{"given":"Quanjun","family":"Xiang","sequence":"first","affiliation":[{"name":"College of Resources and Environment Huazhong Agricultural University  Wuhan 430070 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feiyue","family":"Cheng","sequence":"additional","affiliation":[{"name":"College of Resources and Environment Huazhong Agricultural University  Wuhan 430070 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Di","family":"Lang","sequence":"additional","affiliation":[{"name":"College of Resources and Environment Huazhong Agricultural University  Wuhan 430070 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,4,5]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr1001645"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/B800489G"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/238037a0"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progsolidstchem.2004.08.001"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja302846n"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2013.03.005"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201403062"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2317"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp200953k"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2025454"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3DT53601G"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2013.05.131"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1gc15465f"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl202587b"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0gc00236d"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC47301E"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn102469e"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15172J"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz302048d"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411096"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201411096"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201301925"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn5019945"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC04653F"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm15791h"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC02553A"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1141483"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1215868"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja201269b"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/am403663f"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402315"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201402315"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410172"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201410172"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja506261t"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp2006777"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2014.03.002"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1nr10610d"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201500010"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201300941"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.5b01610"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp5054474"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2015.08.177"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2015.08.222"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201300685"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2007.02.034"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.200900310"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307475"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201307475"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2013.08.138"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0CP01139H"},{"key":"e_1_2_6_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201402220"},{"key":"e_1_2_6_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja800745y"},{"key":"e_1_2_6_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3nr02920d"},{"key":"e_1_2_6_51_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac198557040603"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2014.06.051"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201501702","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201501702","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201501702","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T11:23:39Z","timestamp":1760354619000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201501702"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,4,5]]},"references-count":56,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2016,5,10]]}},"alternative-id":["10.1002\/cssc.201501702"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201501702","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,4,5]]},"assertion":[{"value":"2015-12-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2016-04-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}