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The aim was to prepare linear polyesters with pendant hydroxyl groups along the polymer backbone. The performance of the sustainable biocatalyst SPRIN liposorb CALB [an immobilized form of <jats:italic>Candida antarctica<\/jats:italic> lipase B (CALB); SPRIN technologies] and the organo\u2010base catalyst 1,5,7\u2010triazabicyclo[4,4,0]dec\u20105\u2010ene (TBD) were compared with two metal\u2010based catalysts: dibutyl tin oxide (DBTO) and scandium trifluoromethanesulfonate [also known as scandium triflate, Sc(OTf)<jats:sub>3<\/jats:sub>]. For the four catalytic systems, the efficiency and selectivity for the incorporation of sorbitol were studied, mainly using <jats:sup>13<\/jats:sup>C and <jats:sup>31<\/jats:sup>P\u2005NMR spectroscopies, whereas side reactions, such as ether formation and dehydration of sorbitol, were evaluated using MALDI\u2010TOF\u2010MS. Especially the biocatalyst SPRIN liposorb CALB succeeded in incorporating sorbitol in a selective way without side reactions, leading to close\u2010to\u2010linear polyesters. By using a renewable hydroxyl\u2010reactive curing agent based on <jats:sc>l<\/jats:sc>\u2010lysine, transparent and glossy poly(ester urethane) networks were successfully synthesized offering a tangible example of bio\u2010based coatings.<\/jats:p>","DOI":"10.1002\/cssc.201600626","type":"journal-article","created":{"date-parts":[[2016,7,13]],"date-time":"2016-07-13T05:02:37Z","timestamp":1468386157000},"page":"2250-2260","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Green and selective polycondensation methods toward linear sorbitol\u2010based polyesters: enzymatic versus organic and metal\u2010based catalysis"],"prefix":"10.1002","volume":"9","author":[{"given":"Liliana","family":"Gustini","sequence":"first","affiliation":[{"name":"Laboratory of Physical Chemistry Eindhoven University of Technology  P.O. Box 513 5600 MB Eindhoven Netherlands"},{"name":"Dutch Polymer Institute  P.O. 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