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However, the photocatalytic conversion efficiency is often limited by the sluggish transfer of the photogenerated charge carriers, charge recombination, and subsequent slow catalytic reactions. Herein, we report a highly active noble\u2010metal\u2010free photocatalytic system for hydrogen production in water. The system contains a water\u2010soluble nickel complex as a molecular cocatalyst and zinc sulfide on 1D cadmium sulfide as the heterojunction photocatalyst. The complex can efficiently transport photogenerated electrons and holes over a heterojunction photocatalyst to hamper charge recombination, leading to highly improved catalytic efficiency and durability of a heterojunction photocatalyst\u2013 molecular cocatalyst system. The results show that under optimal conditions, the average apparent quantum yield was approximately 58.3\u2009% after 7\u2005h of irradiation with monochromatic 420\u2005nm light. In contrast, the value is only 16.8\u2009% if the molecular cocatalyst is absent. Such a remarkable performance in a molecular cocatalyst\u2010based photocatalytic system without any noble metal loading has, to the best of our knowledge, not been reported to date.<\/jats:p>","DOI":"10.1002\/cssc.201600871","type":"journal-article","created":{"date-parts":[[2016,10,13]],"date-time":"2016-10-13T14:13:17Z","timestamp":1476367997000},"page":"3084-3092","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Synergistic Effect of a Molecular Cocatalyst and a Heterojunction in a 1\u2009D Semiconductor Photocatalyst for Robust and Highly Efficient Solar Hydrogen Production"],"prefix":"10.1002","volume":"9","author":[{"given":"Daochuan","family":"Jiang","sequence":"first","affiliation":[{"name":"Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences, Department of Materials Science and Engineering, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) University of Science and Technology of China  96 Jinzhai Road 230026 Hefei Anhui Province P.R. 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