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Of all the as\u2010prepared catalysts, bimetallic Cu\u2010Pd catalysts showed the highest catalytic activities towards the formation of 2\u2010MF and 2\u2010MTHF with a total yield of up to 83.9\u2009% yield at 220\u2009\u00b0C in 4\u2005h. By modifying the Pd ratios in the Cu\u2010Pd catalyst, 2\u2010MF or 2\u2010MTHF could be obtained selectively as the prevailing product. The other reaction conditions also had a great influence on the product distribution. Mechanistic studies by reaction monitoring and intermediate conversion revealed that the reaction proceeded mainly through the hydrogenation of furfural to furfuryl alcohol, which was followed by deoxygenation to 2\u2010MF in parallel to deoxygenation\/ring hydrogenation to 2\u2010MTHF. Finally, the catalyst showed a high reactivity and stability in five catalyst recycling runs, which represents a significant step forward toward the catalytic transfer hydrogenation of furfural.<\/jats:p>","DOI":"10.1002\/cssc.201601122","type":"journal-article","created":{"date-parts":[[2016,11,9]],"date-time":"2016-11-09T23:50:50Z","timestamp":1478735450000},"page":"3330-3337","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":173,"title":["Catalytic Transfer Hydrogenation of Furfural to 2\u2010Methylfuran and 2\u2010Methyltetrahydrofuran over Bimetallic Copper\u2013Palladium Catalysts"],"prefix":"10.1002","volume":"9","author":[{"given":"Xin","family":"Chang","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering Nanjing Forestry University  Longpan Road Nanjing 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