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Herein, a three\u2010dimensional (3D) architecture consisting of CuO nanosheets supported onto transparent conducting macroporous antimony\u2010doped tin oxide (mpATO@CuONSs) is designed as an excellent photocathode for promoting the hydrogen evolution reaction (HER). Owing to the 3D structure affording superior light\u2010harvesting characteristics, large contact areas with the electrolyte, and highly conductive pathways for separation and transport of charge carriers, the mpATO@CuONSs photocathode produces an impressively high photocurrent density of \u22124.6\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup> at 0\u2005V versus the reversible hydrogen electrode (RHE), which is much higher than that of the CuONSs array onto planar FTO glass (\u22121.9\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup>).<\/jats:p>","DOI":"10.1002\/cssc.201601140","type":"journal-article","created":{"date-parts":[[2016,10,12]],"date-time":"2016-10-12T14:31:02Z","timestamp":1476282662000},"page":"3012-3018","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["3D Cathodes of Cupric Oxide Nanosheets Coated onto Macroporous Antimony\u2010Doped Tin Oxide for Photoelectrochemical Water Splitting"],"prefix":"10.1002","volume":"9","author":[{"given":"Xu\u2010Dong","family":"Wang","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University  Guangzhou 510275 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang\u2010Fan","family":"Xu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University  Guangzhou 510275 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bai\u2010Xue","family":"Chen","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University  Guangzhou 510275 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ning","family":"Zhou","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University  Guangzhou 510275 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong\u2010Yan","family":"Chen","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University  Guangzhou 510275 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dai\u2010Bin","family":"Kuang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University  Guangzhou 510275 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng\u2010Yong","family":"Su","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University  Guangzhou 510275 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,10,5]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201000416"},{"key":"e_1_2_6_2_1","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201402477"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201401082"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssi.2004.04.028"},{"key":"e_1_2_6_6_1","unstructured":"\u00a0"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2003.09.015"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.1789155"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.3614408"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.330567"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie202522g"},{"key":"e_1_2_6_12_1","unstructured":"\u00a0"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201201474"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b09613"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl5020958"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc04985a"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep10838"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta13299d"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CP03132F"},{"key":"e_1_2_6_20_1","unstructured":"\u00a0"},{"key":"e_1_2_6_21_2","first-page":"2072","volume":"43","author":"Wadia C.","year":"2009","journal-title":"Energy Environ. 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