{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T23:00:52Z","timestamp":1790118052645,"version":"4.0.1"},"reference-count":68,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2016,12,22]],"date-time":"2016-12-22T00:00:00Z","timestamp":1482364800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2017,2,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A combined sonication and microwave irradiation procedure provides the most effective functionalization of ethylenediamine (en) and branched primary diamines of 1\u2010methylethylenediamine (men) and 1,1\u2010dimethylethylenediamine (den) onto the open metal sites of Mg<jats:sub>2<\/jats:sub>(dobpdc) (<jats:bold>1<\/jats:bold>). The CO<jats:sub>2<\/jats:sub> capacities of the advanced adsorbents <jats:bold>1\u2010en<\/jats:bold> and <jats:bold>1\u2010men<\/jats:bold> under simulated flue gas conditions are 19\u2005wt\u2009% and 17.4\u2005wt\u2009%, respectively, which are the highest values reported among amine\u2010functionalized metal\u2010organic frameworks (MOFs) to date. Moreover, <jats:bold>1\u2010den<\/jats:bold> exhibits both a significant working capacity (12.2\u2005wt\u2009%) and superb CO<jats:sub>2<\/jats:sub> uptake (11\u2005wt\u2009%) at 3\u2009% CO<jats:sub>2<\/jats:sub>. Additionally, this framework showcases the superior recyclability; ultrahigh stability after exposure to O<jats:sub>2<\/jats:sub>, moisture, and SO<jats:sub>2<\/jats:sub>; and exceptional CO<jats:sub>2<\/jats:sub> adsorption capacity under humid conditions, which are unprecedented among MOFs. We also elucidate that the performance of CO<jats:sub>2<\/jats:sub> adsorption can be controlled by the structure of the diamine ligands grafted such as the number of amine end groups or the presence of side groups, which provides the first systematic and comprehensive demonstration of fine\u2010tuning of CO<jats:sub>2<\/jats:sub> uptake capability using different amines.<\/jats:p>","DOI":"10.1002\/cssc.201601203","type":"journal-article","created":{"date-parts":[[2016,12,22]],"date-time":"2016-12-22T16:56:04Z","timestamp":1482425764000},"page":"541-550","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":118,"title":["Fine\u2010Tuning of the Carbon Dioxide Capture Capability of Diamine\u2010Grafted Metal\u2013Organic Framework Adsorbents Through Amine Functionalization"],"prefix":"10.1002","volume":"10","author":[{"given":"Hyuna","family":"Jo","sequence":"first","affiliation":[{"name":"Department of Chemistry Korea University  Seoul 136-713 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Woo Ram","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemistry Korea University  Seoul 136-713 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nam Woo","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry Korea University  Seoul 136-713 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hyun","family":"Jung","sequence":"additional","affiliation":[{"name":"Center for Computational Science Korea Institute of Science and Technology (KIST)  Seoul 136-791 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kwang Soo","family":"Lim","sequence":"additional","affiliation":[{"name":"Department of Chemistry Korea University  Seoul 136-713 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeong Eun","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry Korea University  Seoul 136-713 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong Won","family":"Kang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Korea University  Seoul 136-713 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanyeong","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Energy Science and Technology Myongji University  Myongji-ro 116, Cheoin-gu, Yongin Gyeonggi-do 449-728 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vishwanath","family":"Hiremath","sequence":"additional","affiliation":[{"name":"Department of Energy Science and Technology Myongji University  Myongji-ro 116, Cheoin-gu, Yongin Gyeonggi-do 449-728 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeong Gil","family":"Seo","sequence":"additional","affiliation":[{"name":"Department of Energy Science and Technology Myongji University  Myongji-ro 116, Cheoin-gu, Yongin Gyeonggi-do 449-728 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hailian","family":"Jin","sequence":"additional","affiliation":[{"name":"Research &amp; Development Team Korea Carbon Capture &amp; Sequestration R&amp;D Center  Daejeon 305-343 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dohyun","family":"Moon","sequence":"additional","affiliation":[{"name":"Beamline Division Pohang Accelerator Laboratory  Pohang, Kyungbuk 790-784 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sang Soo","family":"Han","sequence":"additional","affiliation":[{"name":"Center for Computational Science Korea Institute of Science and Technology (KIST)  Seoul 136-791 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang Seop","family":"Hong","sequence":"additional","affiliation":[{"name":"Department of Chemistry Korea University  Seoul 136-713 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,12,22]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature04095"},{"key":"e_1_2_6_4_1","unstructured":"\u00a0"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr2003272"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1172246"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.enpol.2007.07.001"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400237k"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee21586a"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1176731"},{"key":"e_1_2_6_11_1","unstructured":"\u00a0"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200900036"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000431"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201000431"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0EE00064G"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ghg.1296"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15221A"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4EE00143E"},{"key":"e_1_2_6_18_1","unstructured":"\u00a0"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja300034j"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_6_21_1","unstructured":"\u00a0"},{"key":"e_1_2_6_22_2","first-page":"484","volume":"109","author":"Lu A.-H.","year":"2013","journal-title":"Inorg. Chem."},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CE00321G"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CC35561B"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4032049"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic301463z"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt50896j"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1457"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz300328j"},{"key":"e_1_2_6_30_1","unstructured":"\u00a0"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8036096"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1220131"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2012.11.034"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2014.03.005"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9057234"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1ee01720a"},{"key":"e_1_2_6_37_1","unstructured":"\u00a0"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/la200547k"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp300961j"},{"key":"e_1_2_6_40_1","unstructured":"\u00a0"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3EE42328J"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC01191D"},{"key":"e_1_2_6_43_1","unstructured":"\u00a0"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1sc00354b"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja903411w"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja900555r"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja503296c"},{"key":"e_1_2_6_48_1","unstructured":"\u00a0"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b00838"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature11893"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900144"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14327"},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6796"},{"key":"e_1_2_6_54_1","unstructured":"\u00a0"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/c001173h"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902998"},{"key":"e_1_2_6_56_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902998"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT03710G"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm15887f"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.5b02930"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4004766"},{"key":"e_1_2_6_61_1","unstructured":"\u00a0"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/je1002225"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202176"},{"key":"e_1_2_6_63_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201202176"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA02861A"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA02357B"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201601203","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201601203","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T12:04:05Z","timestamp":1760357045000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201601203"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,12,22]]},"references-count":68,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2017,2,8]]}},"alternative-id":["10.1002\/cssc.201601203"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201601203","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,12,22]]},"assertion":[{"value":"2016-08-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2016-12-22","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}