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The reaction proceeds in acetonitrile and aqueous solutions, at atmospheric pressure and room temperature by irradiation using a low\u2010pressure mercury lamp. This transition\u2010metal\u2010free photocatalytic process for CO<jats:sub>2<\/jats:sub> capture coupled with H<jats:sub>2<\/jats:sub>S removal may have been relevant as a prebiotic carbon dioxide fixation.<\/jats:p>","DOI":"10.1002\/cssc.201601285","type":"journal-article","created":{"date-parts":[[2016,12,7]],"date-time":"2016-12-07T07:59:32Z","timestamp":1481097572000},"page":"3397-3400","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Iodide\u2010Photocatalyzed Reduction of Carbon Dioxide to Formic Acid with Thiols and Hydrogen Sulfide"],"prefix":"10.1002","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9983-3656","authenticated-orcid":false,"given":"Mateo","family":"Berton","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica Universidad de Valencia  Avda. 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