{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T17:18:53Z","timestamp":1792603133579,"version":"4.5.0"},"reference-count":49,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2017,1,9]],"date-time":"2017-01-09T00:00:00Z","timestamp":1483920000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2017,2,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Hyper\u2010crosslinked polymers (HCPs) are promising materials for gas capture and storage, but high cost and complicated preparation limit their practical application. In this paper, a new type of HCPs (CTHPs) was synthesized through a one\u2010step mild Friedel\u2013Crafts reaction with low\u2010cost coal tar as the starting material. Chloroform was utilized as both solvent and crosslinker to generate a three\u2010dimensional crosslinked network with abundant micropores. The maximum BET surface area of the prepared CTHPs could reach up to 929\u2005m<jats:sup>2<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>. Owing to the high affinity between the heteroatoms on the coal\u2010tar building blocks and the CO<jats:sub>2<\/jats:sub> molecules, the adsorption capacity of CTHPs towards CO<jats:sub>2<\/jats:sub> reached up to 14.2\u2005wt\u2009% (1.0\u2005bar, 273\u2005K) with a high selectivity (CO<jats:sub>2<\/jats:sub>\/N<jats:sub>2<\/jats:sub>=32.3). Furthermore, the obtained CTHPs could adsorb 1.27\u2005wt\u2009% H<jats:sub>2<\/jats:sub> at 1.0\u2005bar and 77.3\u2005K, and also showed capacity for the capture of high organic vapors at room temperature. In comparison with other reported porous organic polymers, CTHPs have the advantages of low\u2010cost, easy preparation, and high gas\u2010adsorption performance, making them suitable for mass production and practical use in the future.<\/jats:p>","DOI":"10.1002\/cssc.201601475","type":"journal-article","created":{"date-parts":[[2016,11,24]],"date-time":"2016-11-24T07:43:07Z","timestamp":1479973387000},"page":"618-623","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["Microporous Organic Polymers Based on Hyper\u2010Crosslinked Coal Tar: Preparation and Application for Gas Adsorption"],"prefix":"10.1002","volume":"10","author":[{"given":"Hui","family":"Gao","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering College of Materials Xiamen University  Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Ding","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering College of Materials Xiamen University  Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hua","family":"Bai","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering College of Materials Xiamen University  Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering College of Materials Xiamen University  Xiamen 361005 P. R. China"},{"name":"Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules Shanghai Institute of Organic Chemistry Chinese Academy of Sciences  345 Lingling Road Shanghai 200032 P. R. China"},{"name":"Fujian Provincial Key Laboratory of Materials Genome Xiamen University  Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,1,9]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma400496q"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b01949"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b11955"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2004.06.023"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c004106h"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.5b00544"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b03727"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC10391B"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40507a"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1956"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4611"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5503"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201401001"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC00261G"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200801971"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200701595"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200701595"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b00901"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201500829"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma200630s"},{"key":"e_1_2_6_20_1","unstructured":"V. A.Davankov S. V.Rogozhin M. P.Tsyurupa USSR Pat. 299165 1973."},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja5031968"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.6b00015"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC07908J"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1080\/10406639508009625"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1046\/j.1365-2230.2002.00995.x"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/etc.5620020304"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b00147"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA04429K"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac198557040603"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9015765"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee21935b"},{"key":"e_1_2_6_32_1","first-page":"3","author":"Ren S.","journal-title":"x."},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC08195E"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc00039g"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1sc00100k"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0jm03534c"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm300407h"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm200411p"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4NJ01477D"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm400019f"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201200751"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3py00590a"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200504241"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200504241"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8010176"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm15159f"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1007\/s003390100847"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma501497c"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201601475","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201601475","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T12:03:32Z","timestamp":1760357012000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201601475"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,1,9]]},"references-count":49,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2017,2,8]]}},"alternative-id":["10.1002\/cssc.201601475"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201601475","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,1,9]]},"assertion":[{"value":"2016-10-17","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2017-01-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}