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Depending on the calcination temperatures, SnS<jats:sub>2<\/jats:sub>\u2010based photoelectrodes can either retain their n\u2010type nature with greatly enhanced anodic photocurrent density (ca.\u20051.2\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup> at 0.8\u2005V vs. Ag\/AgCl) or be completely converted into p\u2010type SnS to generate approximately 0.26\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup> cathodic photocurrent density at \u22120.8\u2005V vs. Ag\/AgCl. The dominance of sulfur and tin vacancies are found to account for the dramatically different photoelectrochemical behaviors of n\u2010type SnS<jats:sub>2<\/jats:sub> and p\u2010type SnS photoelectrodes. In addition, the band structures of n\u2010type SnS<jats:sub>2<\/jats:sub> and p\u2010type SnS photoelectrodes are also deduced, which may provide an effective strategy for developing SnS<jats:sub>2<\/jats:sub>\/SnS films with controllable energy\u2010band levels through a simple calcination treatment.<\/jats:p>","DOI":"10.1002\/cssc.201601603","type":"journal-article","created":{"date-parts":[[2016,12,17]],"date-time":"2016-12-17T02:52:13Z","timestamp":1481943133000},"page":"670-674","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Switched Photocurrent on Tin Sulfide\u2010Based Nanoplate Photoelectrodes"],"prefix":"10.1002","volume":"10","author":[{"given":"Hongjun","family":"Chen","sequence":"first","affiliation":[{"name":"Nanomaterials Centre School of Chemical Engineering and Australian, Institute for Bioengineering and Nanotechnology The University of Queensland  Brisbane QLD 4072 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