{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T21:44:53Z","timestamp":1790718293617,"version":"4.1.0"},"reference-count":64,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2017,3,2]],"date-time":"2017-03-02T00:00:00Z","timestamp":1488412800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["2014R1A4A1001690"],"award-info":[{"award-number":["2014R1A4A1001690"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["NRF-2016R1E1A1A01941978"],"award-info":[{"award-number":["NRF-2016R1E1A1A01941978"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2017,4,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Solar\u2010driven photocatalytic hydrogen evolution is important to bring solar\u2010energy\u2010to\u2010fuel energy\u2010conversion processes to reality. However, there is a lack of highly efficient, stable, and non\u2010precious photocatalysts, and catalysts not designed completely with expensive noble metals have remained elusive, which hampers their large\u2010scale industrial application. Herein, for the first time, a highly efficient and stable noble\u2010metal\u2010free CdS\/WS<jats:sub>2<\/jats:sub>\u2010MoS<jats:sub>2<\/jats:sub> nanocomposite was designed through a facile hydrothermal approach. When assessed as a photocatalyst for water splitting, the CdS\/WS<jats:sub>2<\/jats:sub>\u2010MoS<jats:sub>2<\/jats:sub> nanostructures exhibited remarkable photocatalytic hydrogen\u2010evolution performance and impressive durability. An excellent hydrogen evolution rate of 209.79\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup> was achieved under simulated sunlight irradiation, which is higher than the values for CdS\/MoS<jats:sub>2<\/jats:sub> (123.31\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>) and CdS\/WS<jats:sub>2<\/jats:sub> nanostructures (169.82\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>) and the expensive CdS\/Pt benchmark catalyst (34.98\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>). The apparent quantum yield reached 51.4\u2009% at <jats:italic>\u03bb<\/jats:italic>=425\u2005nm in 5\u2005h. Furthermore, the obtained hydrogen evolution rate was better than those of several noble\u2010metal\u2010free catalysts reported previously. The observed high rate of hydrogen evolution and remarkable stability may be a result of the ultrafast separation of photogenerated charge carriers and transport between the CdS nanorods and the WS<jats:sub>2<\/jats:sub>\u2010MoS<jats:sub>2<\/jats:sub> nanosheets, which thus increases the number of electrons involved in hydrogen production. The proposed designed strategy is believed to potentially open a door to the design of advanced noble\u2010metal\u2010free photocatalytic materials for efficient solar\u2010driven hydrogen production.<\/jats:p>","DOI":"10.1002\/cssc.201601799","type":"journal-article","created":{"date-parts":[[2017,1,25]],"date-time":"2017-01-25T08:46:45Z","timestamp":1485334005000},"page":"1563-1570","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":166,"title":["Heterostructured WS<sub>2<\/sub>\u2010MoS<sub>2<\/sub> Ultrathin Nanosheets Integrated on CdS Nanorods to Promote Charge Separation and Migration and Improve Solar\u2010Driven Photocatalytic Hydrogen Evolution"],"prefix":"10.1002","volume":"10","author":[{"given":"D. Amaranatha","family":"Reddy","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanbit","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rory","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"D. Praveen","family":"Kumar","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manho","family":"Lim","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tae Kyu","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of 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