{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T19:48:25Z","timestamp":1784749705500,"version":"3.55.0"},"reference-count":73,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2017,4,10]],"date-time":"2017-04-10T00:00:00Z","timestamp":1491782400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Korean National Research Foundation (Nano-Material Fundamental Technology Development","award":["2016M3A7B4909370"],"award-info":[{"award-number":["2016M3A7B4909370"]}]},{"name":"Korean Ministry of the Environment (MOE) as part of the Public Technology Program based on Environmental Policy","award":["2014000160001"],"award-info":[{"award-number":["2014000160001"]}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2017,5,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>CdS\u2010sensitized 1\u2009D Zr:Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanorod arrays were synthesized on fluorine\u2010doped tin oxide substrates by a two\u2010step hydrothermal method. The photoelectrochemical results demonstrate that the current density (4.2\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup> at 0\u2005V vs. Ag\/AgCl) recorded under illumination for the CdS\/1\u2009D Zr:Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> photoanodes is 2.8\u2005time higher than the bare 1\u2009D Zr:Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>. The extended absorbance spectrum, the reduced recombination, and the effective transport of photogenerated holes in CdS to the electrolyte facilitate enhancement in the photoelectrochemical performance. From X\u2010ray photoelectron spectroscopy and TEM observations of the bare and aluminum oxide\u2010treated CdS\/1\u2009D Zr:Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> photoanodes, we could confirm that the 1\u2009D Zr:Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanorods were covered by the CdS layer and Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> layer present on surface of CdS. Furthermore, the photocurrent and stability of the CdS\/1\u2009D Zr:Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanorods was significantly enhanced by Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> compared to bare CdS\/1\u2009D Zr:Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> heterojunction owing to its ability to act as an effective holetransport\u2010 as well as photocorrosion\u2010protecting layer. These remarkable enhancements in light\u2010energy harvesting, improvement in charge transport, and stability directly suggest the usefulness of photoanodes for solar hydrogen generation.<\/jats:p>","DOI":"10.1002\/cssc.201700140","type":"journal-article","created":{"date-parts":[[2017,3,20]],"date-time":"2017-03-20T04:24:50Z","timestamp":1489983890000},"page":"2030-2039","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["CdS\/Zr:Fe<sub>2<\/sub>O<sub>3<\/sub> Nanorod Arrays with Al<sub>2<\/sub>O<sub>3<\/sub> Passivation Layer for Photoelectrochemical Solar Hydrogen Generation"],"prefix":"10.1002","volume":"10","author":[{"given":"Mahadeo A.","family":"Mahadik","sequence":"first","affiliation":[{"name":"Division of Biotechnology, Safety, Environment and Life Science Institute College of Environmental and Bioresource Sciences Chonbuk National University  Iksan 570\u2013752 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arunprabaharan","family":"Subramanian","sequence":"additional","affiliation":[{"name":"Division of Biotechnology, Safety, Environment and Life Science Institute College of Environmental and Bioresource Sciences Chonbuk National University  Iksan 570\u2013752 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hee\u2010Suk","family":"Chung","sequence":"additional","affiliation":[{"name":"Analytical Research Division Korea Basic Science Institute  Jeonju, Jeollabuk-do 54907 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min","family":"Cho","sequence":"additional","affiliation":[{"name":"Division of Biotechnology, Safety, Environment and Life Science Institute College of Environmental and Bioresource Sciences Chonbuk National University  Iksan 570\u2013752 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jum Suk","family":"Jang","sequence":"additional","affiliation":[{"name":"Division of Biotechnology, Safety, Environment and Life Science Institute College of Environmental and Bioresource Sciences Chonbuk National University  Iksan 570\u2013752 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,4,10]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn102469e"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/238037a0"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9016478"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja200800t"},{"key":"e_1_2_6_5_1","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2016.03.062"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2016.12.173"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2011.09.002"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3nr03245k"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl2000743"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl303961c"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0ee00030b"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja050006u"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm300837z"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja803603y"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp066952u"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2005.08.047"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200902234"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2015.01.071"},{"key":"e_1_2_6_20_1","unstructured":"\u00a0"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201402365"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2012.01.154"},{"key":"e_1_2_6_23_1","unstructured":"\u00a0"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.solmat.2016.09.038"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl070430o"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/am4054332"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0JM01372B"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/es9038962"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/am3011516"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51492g"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA11978F"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl2029392"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51287h"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2014.08.005"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA06915C"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA05195A"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc41362d"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2016.08.046"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja302897b"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/am402487h"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp4009652"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/am5029999"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5NJ02947C"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solmat.2014.04.034"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CP04057K"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2012.06.063"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.5.4709"},{"key":"e_1_2_6_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/am501690g"},{"key":"e_1_2_6_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3RA45069D"},{"key":"e_1_2_6_50_1","unstructured":"\u00a0"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tsf.2016.09.020"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2015.12.001"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp210551r"},{"key":"e_1_2_6_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0169-4332(02)01082-6"},{"key":"e_1_2_6_55_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2356995"},{"key":"e_1_2_6_56_1","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3727\/48\/25\/255102"},{"key":"e_1_2_6_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.spmi.2015.03.031"},{"key":"e_1_2_6_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep29907"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/am504662w"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/sia.5677"},{"key":"e_1_2_6_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/elan.201400241"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep06627"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm303206s"},{"key":"e_1_2_6_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108276"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201108276"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2016.05.126"},{"key":"e_1_2_6_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/am501379m"},{"key":"e_1_2_6_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta14443g"},{"key":"e_1_2_6_68_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3021091"},{"key":"e_1_2_6_69_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ce40863a"},{"key":"e_1_2_6_70_1","doi-asserted-by":"publisher","DOI":"10.1039\/b718759a"},{"key":"e_1_2_6_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp512189c"},{"key":"e_1_2_6_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl100250z"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201700140","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201700140","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.201700140","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201700140","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T14:36:07Z","timestamp":1760366167000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201700140"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,4,10]]},"references-count":73,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2017,5,9]]}},"alternative-id":["10.1002\/cssc.201700140"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201700140","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,4,10]]},"assertion":[{"value":"2017-01-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2017-04-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}