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Upon irradiation at 254\u2005nm in the gas phase and in the absence of catalysts or photocatalysts at near room temperature, H<jats:sub>2<\/jats:sub>S splits into stoichiometric amounts of H<jats:sub>2<\/jats:sub> and S with a quantum efficiency close to 50\u2009%. No influence of the presence of CH<jats:sub>4<\/jats:sub> and CO<jats:sub>2<\/jats:sub> (typical components in natural gas and biogas in which H<jats:sub>2<\/jats:sub>S is an unwanted component) on the efficiency of overall H<jats:sub>2<\/jats:sub>S splitting was observed. A mechanism for the H<jats:sub>2<\/jats:sub> and S formation is proposed.<\/jats:p>","DOI":"10.1002\/cssc.201700294","type":"journal-article","created":{"date-parts":[[2017,4,11]],"date-time":"2017-04-11T09:34:18Z","timestamp":1491903258000},"page":"1996-2000","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Gas\u2010Phase Photochemical Overall H<sub>2<\/sub>S Splitting by UV Light Irradiation"],"prefix":"10.1002","volume":"10","author":[{"given":"Herme G.","family":"Baldovi","sequence":"first","affiliation":[{"name":"Departmento de Qu\u00edmica Universitat Polit\u00e8cnica de Val\u00e8ncia  Camino de Vera s\/n 46022 Valencia Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Josep","family":"Albero","sequence":"additional","affiliation":[{"name":"Instituto Universitario de Tecnolog\u00eda Qu\u00edmica, CSIC-UPV Universitat Polit\u00e8cnica de Val\u00e8ncia  Avda. de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Belen","family":"Ferrer","sequence":"additional","affiliation":[{"name":"Departmento de Qu\u00edmica Universitat Polit\u00e8cnica de Val\u00e8ncia  Camino de Vera s\/n 46022 Valencia Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Diego","family":"Mateo","sequence":"additional","affiliation":[{"name":"Instituto Universitario de Tecnolog\u00eda Qu\u00edmica, CSIC-UPV Universitat Polit\u00e8cnica de Val\u00e8ncia  Avda. de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mercedes","family":"Alvaro","sequence":"additional","affiliation":[{"name":"Departmento de Qu\u00edmica Universitat Polit\u00e8cnica de Val\u00e8ncia  Camino de Vera s\/n 46022 Valencia Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9664-493X","authenticated-orcid":false,"given":"Hermenegildo","family":"Garc\u00eda","sequence":"additional","affiliation":[{"name":"Instituto Universitario de Tecnolog\u00eda Qu\u00edmica, CSIC-UPV Universitat Polit\u00e8cnica de Val\u00e8ncia  Avda. de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,4,11]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0016-2361(02)00324-1"},{"key":"e_1_2_6_2_1","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie00040a027"},{"key":"e_1_2_6_4_2","doi-asserted-by":"crossref","unstructured":"T.\u2005A. 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