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However, traditional homogeneous catalysts for such processes are expensive and suffer poor recyclability, so a heterogeneous analogue is highly desired. A novel spatial modulation approach has been developed to fabricate a heterogeneous Pd\u2010metalated nanoporous polymer, which catalyzes the cyanation of aryl halides without need for ligands. The catalyst displays high activity in the synthesis of benzonitriles, including high product yields, excellent stability and recycling, and broad functional\u2010group tolerance.<\/jats:p>","DOI":"10.1002\/cssc.201700329","type":"journal-article","created":{"date-parts":[[2017,3,24]],"date-time":"2017-03-24T05:10:34Z","timestamp":1490332234000},"page":"2348-2351","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Pd\u2010Metalated Conjugated Nanoporous Polycarbazoles for Additive\u2010Free Cyanation of Aryl Halides: Boosting Catalytic Efficiency through Spatial Modulation"],"prefix":"10.1002","volume":"10","author":[{"given":"Shunmin","family":"Ding","sequence":"first","affiliation":[{"name":"Institute of Applied Chemistry, College of Chemistry Nanchang University  Nanchang Jiangxi 330031 P. R. 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