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Recently, it has become clear that a series of \u03b1\u2010hydroxy acids, esters, and lactones can be formed from carbohydrates in alcohol and water solvents using tin\u2010containing catalysts such as Sn\u2010Beta. These compounds are potential building blocks for polyesters bearing additional olefin and alcohol functionalities. An NMR approach was used to identify, quantify, and optimize the formation of these building blocks in the Sn\u2010Beta\u2010catalyzed transformation of abundant carbohydrates. 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